The contribution of ceramography to the development of ceramic spark plug electrode materials for large gas engines

M. Gruber, V. Melcher, W. Harrer, A. Tilz, M. Engelmayer, W. Fimml, A. Wimmer, R. Bermejo
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Abstract

Abstract Large gas engines play a key role in energy supply and transport. Due to emission regulations and high fuel prices, engines achieving both high efficiency and low emissions are required. Development efforts to that effect have resulted in combustion methods relying on lean air-fuel mixtures as well as high ignition pressures. The conditions in the combustion chamber cause high wear on the spark plug electrodes. Conventional electrodes have a limited lifetime and they are expensive due to the use of precious metal alloys. Compared with conventional materials, alternative ceramic electrode materials offer advantages in terms of high thermal stability, high oxidation and corrosion resistance, as well as lower material prices. Disadvantages include insufficient electrical conductivity, brittleness and the difficulty of joining them with metallic materials. In this paper wear and oxidation behavior of selected materials are evaluated, using ceramographic methods. Microsections of the joining zone are used to analyse the change in the microstructure resulting from the bonding process. The results show the strengths, weaknesses and limitations of the selected ceramics as electrode materials, based on ceramographic methods, which helped essentially to understand the oxidation behavior, the bonding process and wear.
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陶瓷成像技术对大型燃气发动机陶瓷火花塞电极材料开发的贡献
摘要 大型燃气发动机在能源供应和运输中发挥着关键作用。由于排放法规和高昂的燃料价格,需要发动机同时实现高效率和低排放。为此进行的开发工作导致燃烧方法依赖于稀薄的空气-燃料混合物和高点火压力。燃烧室内的条件导致火花塞电极磨损严重。传统电极的使用寿命有限,而且由于使用贵金属合金,价格昂贵。与传统材料相比,替代性陶瓷电极材料具有高热稳定性、高抗氧化性和抗腐蚀性等优点,而且材料价格较低。缺点是导电性不足、易碎以及难以与金属材料连接。本文采用陶瓷成像方法对所选材料的磨损和氧化行为进行了评估。接合区的显微切片用于分析接合过程中微观结构的变化。结果显示了所选陶瓷作为电极材料的优缺点和局限性,基于陶瓷成像方法,这有助于从本质上理解氧化行为、接合过程和磨损。
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