Non-Metallic Pipe Solutions with Permeation Barrier for Safe Transport of Energy Production Fluids – Lab Tests and Case Study

Thorsten Spaeth
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Abstract

Non-metallic pipe systems are the perfect option for transporting highly corrosive fluids from oil and gas production which are potentially environmentally hazardous, since they contain volatile organic hydrocarbons. The operation of oil and gas production in agricultural lands is common in Europe and requires permeation tight solutions in order to prevent any kind of environmental contamination. In the past, leakages caused by corrosion damages on carbon steel pipes or by permeation of hydrocarbons through pipes made of high-density polyethylene (HDPE) have resulted in environmental damages. In order to prove the suitability of plastic pipes with an integrated aluminum barrier layer tests over a 4-year time period were done in the context of field- and laboratory trials. For the pilot tests performed in a crude oil production system, the oil and water composition was given by the real case. For the systematic laboratory tests, clearly specified test liquids which came as close to providing a representative sample as possible were used. In order to simulate the most severe conditions conceivable, the test liquids were a saturated solution consisting of various volatile hydrocarbons, some of them also chlorinated, and a mixture of pure volatile hydrocarbons with a 10-per-cent share of aromatic toluene. In contrast to single-layer plastic pipes, the pipes featuring a barrier layer were shown to be resistant to permeation of all of the dissolved volatile organic ingredients examined by the tests. These results could be confirmed by the performed pilot test in Romania. Thus, plastic pipes equipped with a metallic barrier layer can be recommended for loss-free transport of aqueous liquids containing hydrocarbons, such as production water in crude oil. Combined with permanent monitoring for the purpose of damage detection, this non-metallic pipe solution complies with even the strictest environmental requirements, thus enabling oil production in environmental sensitive areas and guarantees reliable protection of the environment.
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用于安全输送能源生产流体的带防渗层的非金属管道解决方案 - 实验室测试和案例研究
非金属管道系统是输送石油和天然气生产过程中产生的高腐蚀性流体的最佳选择,因为这些流体含有挥发性有机碳氢化合物,可能对环境造成危害。在欧洲,在农业用地生产石油和天然气的情况非常普遍,这就需要采用防渗解决方案,以防止任何形式的环境污染。 过去,由于碳钢管道腐蚀损坏或碳氢化合物渗透到高密度聚乙烯(HDPE)管道中造成的泄漏曾导致环境破坏。为了证明内置铝隔离层的塑料管道的适用性,我们进行了为期 4 年的现场和实验室试验。 在原油生产系统中进行的试点试验中,油和水的成分是根据实际情况确定的。在实验室的系统试验中,使用了明确指定的试验液体,这些液体尽可能接近于提供具有代表性的样本。为了模拟可能出现的最恶劣条件,试验液体是由各种挥发性碳氢化合物组成的饱和溶液,其中一些还含有氯化物质,以及纯挥发性碳氢化合物与 10% 的芳香族甲苯的混合物。 与单层塑料管道相比,带有阻隔层的管道可以防止试验中检测到的所有溶解挥发性有机成分的渗透。在罗马尼亚进行的试点试验也证实了这些结果。 因此,配备金属阻隔层的塑料管道可推荐用于无损耗地输送含有碳氢化合物的水性液体,如原油中的生产用水。这种非金属管道解决方案与以检测损坏为目的的永久性监控相结合,甚至可以满足最严格的环境要求,因此可以在环境敏感区域进行石油生产,并确保对环境的可靠保护。
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