{"title":"Machining of TiAl6V4 Using Lubricants Containing Renewable Microalgae-Born Performance Additives","authors":"Thomas Koch, Dominik Wenzel, Ralf Gläbe","doi":"10.2478/ama-2024-0007","DOIUrl":null,"url":null,"abstract":"Abstract Titanium and its alloys represent a special class of materials. A density of 4.81 g/cm3, a tensile strength of over 1,200 MPa, a fatigue strength greater than that of steel, a low modulus of elasticity and its self-passivating, inert surface make titanium an ideal material for lightweight structures in aerospace, marine applications, the chemical industry and medical implants. Although titanium is inert in its oxidised state, its nascent surface created in machining reacts with almost everything in its environment, including the tool. Moreover, its poor thermal conductivity results in high thermal stress on the tools. Overall, these properties lead to high wear rates and result in the requirement for finding a particularised solution for processes such as milling that involve the need to overcome such challenges. Such processes therefore require lubricants with well-selected performance additives. However, most of these performance additives are based on mineral oil and thus come from a non-renewable resource. In the presented work, environmental-friendly alternatives to conventional mineral oil-based performance additives were investigated. Due to the working mechanisms of performance additives in machining, this work focusses on sulphur- and phosphorus-containing polysaccharides and proteins from microalgae. It has been successfully shown that lubricants using extracts from microalgae as performance additives can be used for high-speed milling (HSC) of TiAl6V4. The investigated extracts were able to reach the performance level of conventional additives in terms of tool lifetime and wear. The results obtained show that appropriate alternatives to mineral oil-based additives exist from renewable raw-material sources.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2478/ama-2024-0007","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract Titanium and its alloys represent a special class of materials. A density of 4.81 g/cm3, a tensile strength of over 1,200 MPa, a fatigue strength greater than that of steel, a low modulus of elasticity and its self-passivating, inert surface make titanium an ideal material for lightweight structures in aerospace, marine applications, the chemical industry and medical implants. Although titanium is inert in its oxidised state, its nascent surface created in machining reacts with almost everything in its environment, including the tool. Moreover, its poor thermal conductivity results in high thermal stress on the tools. Overall, these properties lead to high wear rates and result in the requirement for finding a particularised solution for processes such as milling that involve the need to overcome such challenges. Such processes therefore require lubricants with well-selected performance additives. However, most of these performance additives are based on mineral oil and thus come from a non-renewable resource. In the presented work, environmental-friendly alternatives to conventional mineral oil-based performance additives were investigated. Due to the working mechanisms of performance additives in machining, this work focusses on sulphur- and phosphorus-containing polysaccharides and proteins from microalgae. It has been successfully shown that lubricants using extracts from microalgae as performance additives can be used for high-speed milling (HSC) of TiAl6V4. The investigated extracts were able to reach the performance level of conventional additives in terms of tool lifetime and wear. The results obtained show that appropriate alternatives to mineral oil-based additives exist from renewable raw-material sources.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.