Jeyakiruba Palraj , Anthony Arulraj , Sasikumar M , Helen Annal Therese
{"title":"Rapid and stable energy storage using MoN/Mo2N composite electrodes","authors":"Jeyakiruba Palraj , Anthony Arulraj , Sasikumar M , Helen Annal Therese","doi":"10.1016/j.apsadv.2024.100579","DOIUrl":null,"url":null,"abstract":"<div><p>Molybdenum nitride-based composites, specifically the two-dimensional MoN/Mo<sub>2</sub>N variants, emerge as promising electrode materials for next-generation energy storage devices. This research presents a facile synthesis approach involving a mechanochemical method followed by heat treatment at 900 ֯C in a nitrogen atmosphere to produce the MoN/Mo<sub>2</sub>N composite material. Crystallographic analysis using X-ray diffraction (XRD) and morphological characterization <em>via</em> high-resolution scanning electron microscopy (HRSEM) were conducted. The electrochemical evaluation demonstrated remarkable supercapacitor performance, with a specific capacitance of 306.7 F/g at 1 A/g, highlighting exceptional charge storage capacity. Even at a higher current density of 2 A/g, the composite maintained substantial reversible capacity (198.6 F/g), higher capacitance retention (95.7 %), and Coulombic efficiency (86.2 %) over 6000 cycles, showcasing its robust stability. At a challenging current density of 10 A/g, the specific capacitance remained high at 85.4 F/g. Detailed charge storage mechanism analysis, employing the Dunn method, revealed a complex interplay of capacitive and diffusive processes. Particularly noteworthy was the predominance of capacitive behavior, constituting 78.4 % at an accelerated scan rate of 100 mV/s. This observation underscores the material's advantageous propensity for a higher proportion of capacitive behavior in the charge storage mechanism at elevated scan rates, making it well-suited for applications requiring rapid energy storage and release.</p></div>","PeriodicalId":34303,"journal":{"name":"Applied Surface Science Advances","volume":"19 ","pages":"Article 100579"},"PeriodicalIF":7.5000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666523924000072/pdfft?md5=38af1a7d8a3d2cc225ada43578b44335&pid=1-s2.0-S2666523924000072-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Surface Science Advances","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666523924000072","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Molybdenum nitride-based composites, specifically the two-dimensional MoN/Mo2N variants, emerge as promising electrode materials for next-generation energy storage devices. This research presents a facile synthesis approach involving a mechanochemical method followed by heat treatment at 900 ֯C in a nitrogen atmosphere to produce the MoN/Mo2N composite material. Crystallographic analysis using X-ray diffraction (XRD) and morphological characterization via high-resolution scanning electron microscopy (HRSEM) were conducted. The electrochemical evaluation demonstrated remarkable supercapacitor performance, with a specific capacitance of 306.7 F/g at 1 A/g, highlighting exceptional charge storage capacity. Even at a higher current density of 2 A/g, the composite maintained substantial reversible capacity (198.6 F/g), higher capacitance retention (95.7 %), and Coulombic efficiency (86.2 %) over 6000 cycles, showcasing its robust stability. At a challenging current density of 10 A/g, the specific capacitance remained high at 85.4 F/g. Detailed charge storage mechanism analysis, employing the Dunn method, revealed a complex interplay of capacitive and diffusive processes. Particularly noteworthy was the predominance of capacitive behavior, constituting 78.4 % at an accelerated scan rate of 100 mV/s. This observation underscores the material's advantageous propensity for a higher proportion of capacitive behavior in the charge storage mechanism at elevated scan rates, making it well-suited for applications requiring rapid energy storage and release.