Structural Transformations and Formation of Microstructures and Nanostructures in Thin Films of Chalcogenide Vitreous Semiconductors

IF 0.8 Q3 Engineering Nanotechnologies in Russia Pub Date : 2024-02-08 DOI:10.1134/s2635167623600542
S. V. Zabotnov, P. K. Kashkarov, A. V. Kolobov, S. A. Kozyukhin
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Abstract

Chalcogenide vitreous semiconductors (ChVSs) are of both fundamental and applied interest as materials in which reversible structural transformations within the amorphous phase and phase transitions to the crystalline state can be effectively implemented and various microstructures and nanostructures can be obtained as a result of external effects. One of the most promising methods for such ChVS modifications is the pulsed-laser-irradiation technique, which is a noncontact technology of local impact and makes it possible to change the structural, optical, and electrical properties of samples in a wide range. This includes methods based on the precision formation of a surface microrelief and nanorelief, and high contrast in the conductivity and refractive index between the crystalline and amorphous phases. This work reviews key publications on the structural modification of thin films from the most widely studied binary and ternary ChVS compounds (As2S3, As2Se3, Ge2Sb2Te5, etc.) to show the use of irradiated samples as metasurfaces for photonic applications and promising phase-change data storage.

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钙钛矿半导体薄膜的结构转变以及微结构和纳米结构的形成
摘要钙化玻璃体半导体(ChVS)是一种具有基础和应用价值的材料,在这种材料中,可以有效地实现非晶相内的可逆结构转变和向晶体态的相变,并在外部效应的作用下获得各种微结构和纳米结构。脉冲激光辐照技术是此类 ChVS 改造最有前途的方法之一,它是一种非接触式的局部影响技术,可以在很大范围内改变样品的结构、光学和电学特性。这包括基于精确形成表面微凹凸和纳米凹凸的方法,以及结晶相和非晶相之间电导率和折射率的高对比度。这篇论文回顾了有关二元和三元 ChVS 化合物(As2S3、As2Se3、Ge2Sb2Te5 等)薄膜结构改性的重要文献,展示了将辐照样品用作光子应用的元表面以及相变数据存储的前景。
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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
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0.00%
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期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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