Changes in the Microstructure and Electrochemical Behavior of Pt/C Electrocatalysts under Various Stress Testing Conditions

IF 0.8 Q3 Engineering Nanotechnologies in Russia Pub Date : 2024-03-23 DOI:10.1134/S2635167624600081
E. A. Moguchikh, A. A. Alekseenko, I. V. Pankov, D. V. Alekseenko, V. E. Guterman
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Abstract

A comparative analysis of the microstructure and electrochemical behavior of platinum–carbon electrocatalysts containing 20 and 40% platinum from different manufacturers for fuel cells with a proton-exchange membrane is carried out. The degree of degradation of the catalysts during accelerated stress testing in laboratory conditions is assessed based on the results of not only residual functional characteristics, but also microstructural parameters after electrochemical tests. It is determined that 20 and 40% PM series catalysts contain smaller platinum nanoparticles, characterized by a narrower size and more uniform spatial distribution, compared to analogues of the HiSPEC series. Due to these microstructural features, a PM-series platinum–carbon catalysts are characterized by a higher electrochemically active surface area (EASA) and mass activity values initially and after stress testing.

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各种应力测试条件下 Pt/C 电催化剂微观结构和电化学行为的变化
摘要 对不同制造商生产的用于质子交换膜燃料电池的含 20% 和 40% 铂的铂碳电催化剂的微观结构和电化学行为进行了比较分析。在实验室条件下进行加速应力测试时,催化剂的降解程度不仅基于残余功能特性的结果,还基于电化学测试后的微观结构参数。结果表明,与 HiSPEC 系列催化剂相比,20% 和 40% PM 系列催化剂含有更小的铂纳米颗粒,其特点是尺寸更窄、空间分布更均匀。由于这些微观结构特征,PM 系列铂碳催化剂的电化学活性表面积(EASA)和质量活性值在初始和应力测试后都较高。
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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
自引率
0.00%
发文量
0
期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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