Polychrome Bronze Sculpture: A Multi-Analytical Approach to Unveil the Renaissance Gilded Eagles in the Abbey of San Miniato al Monte, Florence

Heritage Pub Date : 2024-02-14 DOI:10.3390/heritage7020047
E. Cantisani, Nicola Salvioli, Barbara Salvadori
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Abstract

The gilded bronze eagles that stand upon the summit of the Tabernacle by Michelozzo in the Abbey of San Miniato al Monte, Florence (Italy) are an exquisite example of Italian Renaissance sculpture. Commissioned by Piero di Cosimo de Medici, the two eagles, representing the ancient Arte di Calimala, were cast and decorated by Maso di Bartolomeo in the 1448–1449 period. A multi-analytical approach was set up to characterize the state of conservation, materials used, and artistic technique of the eagles. Non-invasive methods were used and integrated with micro-invasive analyses, such as X-ray fluorescence (XRF) and Fourier-transform infrared (FTIR) spectroscopy, X-ray diffractometry on powders (XRPD), scanning electron microscopy coupled with EDS (SEM-EDS), and metallographic investigation. The results depict shiny-looking eagles, suggesting the use of oil gilding on almost all surfaces and revealing the presence of polychromies, which is almost unusual in XV-century bronze statuary and is initially hidden by deposits and corrosion products. Indeed, the paws were originally painted with azurite, while the use of cinnabar imparted a vivid red color to the tongue. A black paint containing mercury was found on the eyes and talons. The bales of cloth were decorated with silver, which is now almost completely lost and whose remains are not visible due to being tarnished, while fine details in gold were detected on the lanyard.
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多色青铜雕塑:用多种分析方法揭开佛罗伦萨圣米尼亚托修道院文艺复兴时期镀金鹰的神秘面纱
矗立在意大利佛罗伦萨圣米尼亚托山顶修道院米切洛佐所作会幕顶端的镀金铜鹰是意大利文艺复兴时期雕塑的精美典范。受皮耶罗-迪-科西莫-德-美第奇(Piero di Cosimo de Medici)的委托,马索-迪-巴托洛梅奥(Maso di Bartolomeo)于 1448-1449 年期间铸造并装饰了这两只代表古代 Calimala 艺术的老鹰。为确定这两只鹰的保存状况、所用材料和艺术技巧,采用了多种分析方法。使用了非侵入性方法,并将其与微侵入性分析相结合,如 X 射线荧光 (XRF) 和傅立叶变换红外 (FTIR) 光谱、粉末 X 射线衍射仪 (XRPD)、扫描电子显微镜与 EDS (SEM-EDS) 以及金相学调查。研究结果表明,老鹰外表光亮,几乎所有表面都使用了油鎏金,并显示出多色的存在,这在十五世纪的青铜雕像中几乎是不常见的,最初会被沉积物和腐蚀产物所掩盖。事实上,爪子最初是用天青石绘制的,而朱砂的使用则为舌头赋予了鲜艳的红色。在眼睛和爪子上发现了含汞的黑色颜料。布包上有银质装饰,现在银质装饰几乎完全消失,其残留物也因被玷污而不可见,而在挂绳上则发现了金质的精美细节。
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