Phosphorus-Containing Polymer Electrolytes for Li Batteries

N. Varan, P. Mergheş, N. Pleşu, L. Macarie, G. Ilia, V. Simulescu
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Abstract

Lithium-ion polymer batteries, also known as lithium-polymer, abbreviated Li-po, are one of the main research topics nowadays in the field of energy storage. This review focuses on the use of the phosphorus containing compounds in Li-po batteries, such as polyphosphonates and polyphosphazenes. Li-po batteries are mini-devices, capable of providing power for any portable gadget. From a constructive point of view, Li-po batteries contain an anode (carbon), a cathode (metal oxide), and a polymer electrolyte, which could be liquid electrolytes or solid electrolytes. In general, a divider is used to keep the anode and cathode from touching each other directly. Since liquid electrolytes have a generally high ionic conductivity, they are frequently employed in Li-ion batteries. In the last decade, the research in this field has also focused on solving safety issues, such as the leakage of electrolytes and risk of ignition due to volatile and flammable organic solvents. The research topics in the field of Li-po remain focused on solving safety problems and improving performance.
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用于锂电池的含磷聚合物电解质
锂离子聚合物电池,又称锂聚合物电池,简称锂聚合物电池,是当今储能领域的主要研究课题之一。本综述重点介绍含磷化合物在锂离子聚合物电池中的应用,如聚膦酸盐和聚磷氮。锂离子电池是一种微型设备,能够为任何便携式小工具提供电力。从结构的角度来看,锂离子电池包含阳极(碳)、阴极(金属氧化物)和聚合物电解质,聚合物电解质可以是液态电解质,也可以是固态电解质。一般来说,隔板用于防止阳极和阴极直接接触。由于液态电解质通常具有较高的离子导电性,因此经常被用于锂离子电池中。近十年来,该领域的研究还侧重于解决安全问题,如电解质泄漏以及挥发性和易燃有机溶剂导致的点火风险。锂离子电池领域的研究课题仍然以解决安全问题和提高性能为重点。
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