{"title":"Epitaxial tantalum‐doped β‐Ga2O3 thin films grown on MgO (001) substrate by pulsed laser deposition","authors":"Haobo Lin, Ningtao Liu, Wei Wang, Xiaoli Zhang, Dongyang Han, Wenrui Zhang, Jichun Ye","doi":"10.1002/pssr.202400023","DOIUrl":null,"url":null,"abstract":"Epitaxial thin films of tantalum‐doped β‐Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> (Ta‐Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>) were grown on MgO (001) substrates to study the effect of Ta doping on the electrical properties of β‐Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> films. X‐ray diffraction measurements show that the films with different Ta doping concentrations are (00<jats:italic>l</jats:italic>)‐oriented single‐crystalline β‐Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> without impurity phases. The incorporation of the Ta element modifies the electrical properties of Ta‐Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> films significantly. At a very low doping ratio of 0.05 mol%, the Ta‐Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> film showed a minimum resistivity of 2.32 Ω·cm and a carrier concentration of 2.48×10<jats:sup>17</jats:sup> cm<jats:sup>‐3</jats:sup>. The corresponding activation energy of Ta element in the film was 16.8 meV, suggesting that the Ta element is a promising shallow donor dopant. The XPS analysis confirms that the Fermi level of the Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> films shifts towards the conduction band minimum after the introduction of Ta ions. These results indicate that the transition metal element Ta could be an effective n‐type dopant for modulating the carrier transport behavior of β‐Ga<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> films.This article is protected by copyright. All rights reserved.","PeriodicalId":54619,"journal":{"name":"Physica Status Solidi-Rapid Research Letters","volume":null,"pages":null},"PeriodicalIF":2.5000,"publicationDate":"2024-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica Status Solidi-Rapid Research Letters","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1002/pssr.202400023","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
Epitaxial thin films of tantalum‐doped β‐Ga2O3 (Ta‐Ga2O3) were grown on MgO (001) substrates to study the effect of Ta doping on the electrical properties of β‐Ga2O3 films. X‐ray diffraction measurements show that the films with different Ta doping concentrations are (00l)‐oriented single‐crystalline β‐Ga2O3 without impurity phases. The incorporation of the Ta element modifies the electrical properties of Ta‐Ga2O3 films significantly. At a very low doping ratio of 0.05 mol%, the Ta‐Ga2O3 film showed a minimum resistivity of 2.32 Ω·cm and a carrier concentration of 2.48×1017 cm‐3. The corresponding activation energy of Ta element in the film was 16.8 meV, suggesting that the Ta element is a promising shallow donor dopant. The XPS analysis confirms that the Fermi level of the Ga2O3 films shifts towards the conduction band minimum after the introduction of Ta ions. These results indicate that the transition metal element Ta could be an effective n‐type dopant for modulating the carrier transport behavior of β‐Ga2O3 films.This article is protected by copyright. All rights reserved.
期刊介绍:
Physica status solidi (RRL) - Rapid Research Letters was designed to offer extremely fast publication times and is currently one of the fastest double peer-reviewed publication media in solid state and materials physics. Average times are 11 days from submission to first editorial decision, and 12 days from acceptance to online publication. It communicates important findings with a high degree of novelty and need for express publication, as well as other results of immediate interest to the solid-state physics and materials science community. Published Letters require approval by at least two independent reviewers.
The journal covers topics such as preparation, structure and simulation of advanced materials, theoretical and experimental investigations of the atomistic and electronic structure, optical, magnetic, superconducting, ferroelectric and other properties of solids, nanostructures and low-dimensional systems as well as device applications. Rapid Research Letters particularly invites papers from interdisciplinary and emerging new areas of research.