Determination of 58Fe/54Fe isotope ratios in Chang’E-5 lunar regolith by instrumental neutron activation analysis

Nuclear Analysis Pub Date : 2024-03-01 Epub Date: 2024-02-29 DOI:10.1016/j.nucana.2024.100102
Yonggang Yao, Caijin Xiao, Liang Zhao, Yuqing Li, Tianfu Li, Bing Guo, Dongfeng Chen
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Abstract

Traditionally, the determination of isotope ratios is analyzed by mass spectrometry (MS) method, which is usually destructive to sample (i.e., sample dissolution). Furthermore, the 58Fe abundance (0.282%) is generally rather low relative to other Fe isotopes, therefore, 58Fe/54Fe results is not reported in the routine measurement for MS methods. Given the importance of investigating a possible genetic relationship between the stable isotope composition of the Moon and the Earth, here, we firstly report the isotope ratios of 58Fe/54Fe in the Chang’E-5 (CE-5) scooped bulk lunar sample. In this work, the 58Fe/54Fe ratios were analyzed by instrumental neutron activation analysis (INAA) which is essentially distinguished and a potentially complementary advantage for MS in the determination of stable isotope ratios. These data obtained for the CE-5 lunar sample were also compared with those of terrestrial sample GBW07105.

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利用仪器中子活化分析测定嫦娥五号月球碎屑中的 58Fe/54Fe 同位素比率
传统上,同位素比值的测定是通过质谱法(MS)进行分析的,而质谱法通常对样品具有破坏性(即样品溶解)。此外,58Fe 丰度(0.282%)相对于其他铁同位素而言通常较低,因此在质谱法的常规测量中没有报告 58Fe/54Fe 的结果。鉴于研究月球与地球稳定同位素组成之间可能存在的遗传关系的重要性,我们在此首次报告了嫦娥五号(CE-5)舀取的块状月球样品中 58Fe/54Fe 的同位素比值。在这项工作中,58Fe/54Fe的比值是通过仪器中子活化分析(INAA)进行分析的,INAA与MS在测定稳定同位素比值方面有着本质的区别和潜在的互补优势。CE-5 月球样品获得的这些数据还与地面样品 GBW07105 的数据进行了比较。
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