Adsorption Properties of Beta Carotene from Activated Carbon Derivatives of Oil Palm Empty Bunches

Jasmidi Jasmidi, M. Zubir, R. Selly, P. Faradilla, Siti Rahmah
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Abstract

This research aims to determine the adsorption ability of activated carbon and Fe-Cu modified activated carbon in the β-carotene adsorption process on Crude Palm Oil (CPO). Empty Palm Oil Bunches (TKKS) are used as a bio-sorbent for carbon production at a temperature of 500 ºC. The synthesized carbon was activated using H3PO4 and modified with Fe-Cu metal. CPO quality parameters such as Free Fatty Acids and Peroxide Number were analyzed to see the effect of adsorption on CPO quality. The β-carotene level in the CPO sample used is 472.1 ppm. The optimum conditions for using activated carbon in the β-carotene adsorption process are a mass variation of 8 grams with the β-carotene remaining after adsorption being 432.4 ppm, whereas by using Magnetic Activated Carbon, CPO β-carotene after adsorption remains at 426.1 ppm. Meanwhile, increasing the adsorption time causes the absorption of β-carotene to become greater. By using Activated Carbon the remaining β-carotene is 300.1 ppm after 120 minutes, whereas by using Magnetic Activated Carbon the optimum absorption time is faster and the amount of β-carotene absorbed is greater. The remaining βcarotene after absorption with Magnetic Activated Carbon was 288.7 after 90 minutes of adsorption. Apart from being able to absorb β-carotene, magnetic activated carbon is also better at reducing FFA and PV levels from CPO.
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油棕空枝活性炭衍生物对β-胡萝卜素的吸附特性
本研究旨在确定活性炭和铁铜改性活性炭在粗棕榈油(CPO)β-胡萝卜素吸附过程中的吸附能力。空棕榈油束(TKKS)被用作生物吸附剂,在 500 ºC 的温度下进行制炭。合成的碳使用 H3PO4 进行活化,并用铁-铜金属进行改性。分析了游离脂肪酸和过氧化值等 CPO 质量参数,以了解吸附对 CPO 质量的影响。所用 CPO 样品中的β-胡萝卜素含量为 472.1 ppm。在 β-胡萝卜素吸附过程中使用活性炭的最佳条件是质量变化为 8 克,吸附后剩余的 β-胡萝卜素为 432.4 ppm,而使用磁性活性炭,吸附后 CPO β-胡萝卜素保持在 426.1 ppm。同时,随着吸附时间的延长,β-胡萝卜素的吸收量也会增加。使用活性炭时,120 分钟后剩余的 β 胡萝卜素为 300.1 ppm,而使用磁性活性炭时,最佳吸收时间更快,吸收的 β 胡萝卜素也更多。使用磁性活性炭吸收后,经过 90 分钟的吸附,剩余的 β 胡萝卜素为 288.7。除了能吸收 β 胡萝卜素,磁性活性炭还能更好地降低 CPO 中的 FFA 和 PV 含量。
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