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Adsorption Properties of Beta Carotene from Activated Carbon Derivatives of Oil Palm Empty Bunches 油棕空枝活性炭衍生物对β-胡萝卜素的吸附特性
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56436
Jasmidi Jasmidi, M. Zubir, R. Selly, P. Faradilla, Siti Rahmah
This research aims to determine the adsorption ability of activated carbon and Fe-Cu modified activated carbon in the β-carotene adsorption process on Crude Palm Oil (CPO). Empty Palm Oil Bunches (TKKS) are used as a bio-sorbent for carbon production at a temperature of 500 ºC. The synthesized carbon was activated using H3PO4 and modified with Fe-Cu metal. CPO quality parameters such as Free Fatty Acids and Peroxide Number were analyzed to see the effect of adsorption on CPO quality. The β-carotene level in the CPO sample used is 472.1 ppm. The optimum conditions for using activated carbon in the β-carotene adsorption process are a mass variation of 8 grams with the β-carotene remaining after adsorption being 432.4 ppm, whereas by using Magnetic Activated Carbon, CPO β-carotene after adsorption remains at 426.1 ppm. Meanwhile, increasing the adsorption time causes the absorption of β-carotene to become greater. By using Activated Carbon the remaining β-carotene is 300.1 ppm after 120 minutes, whereas by using Magnetic Activated Carbon the optimum absorption time is faster and the amount of β-carotene absorbed is greater. The remaining βcarotene after absorption with Magnetic Activated Carbon was 288.7 after 90 minutes of adsorption. Apart from being able to absorb β-carotene, magnetic activated carbon is also better at reducing FFA and PV levels from CPO.
本研究旨在确定活性炭和铁铜改性活性炭在粗棕榈油(CPO)β-胡萝卜素吸附过程中的吸附能力。空棕榈油束(TKKS)被用作生物吸附剂,在 500 ºC 的温度下进行制炭。合成的碳使用 H3PO4 进行活化,并用铁-铜金属进行改性。分析了游离脂肪酸和过氧化值等 CPO 质量参数,以了解吸附对 CPO 质量的影响。所用 CPO 样品中的β-胡萝卜素含量为 472.1 ppm。在 β-胡萝卜素吸附过程中使用活性炭的最佳条件是质量变化为 8 克,吸附后剩余的 β-胡萝卜素为 432.4 ppm,而使用磁性活性炭,吸附后 CPO β-胡萝卜素保持在 426.1 ppm。同时,随着吸附时间的延长,β-胡萝卜素的吸收量也会增加。使用活性炭时,120 分钟后剩余的 β 胡萝卜素为 300.1 ppm,而使用磁性活性炭时,最佳吸收时间更快,吸收的 β 胡萝卜素也更多。使用磁性活性炭吸收后,经过 90 分钟的吸附,剩余的 β 胡萝卜素为 288.7。除了能吸收 β 胡萝卜素,磁性活性炭还能更好地降低 CPO 中的 FFA 和 PV 含量。
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引用次数: 0
Formulation and Physical Stability Test of Shampoo Preparation Combination of Ethanol Extract of Jackfruit Leaves (Artocarpus heterophyllus) and Pandan Leaves (Pandanus Amaryllifolius) with Varying Carbomer Concentrations 不同卡波姆浓度的积雪果叶(Artocarpus heterophyllus)和潘丹叶(Pandanus Amaryllifolius)乙醇提取物组合洗发水制剂的配方和物理稳定性测试
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56446
Febrilliani Kharisma Kessya, Rosaria Ika Pratiwi, Rizki Febriyanti
Hair plays an important role for humans because hair can influence a person's appearance. Pandan leaves (Pandanus Amaryllifolius) contain compounds in the form of alkaloids, flavonoids, saponins, polyphenols, tannins and dyes. In pandan leaves, the compounds that can provide antimicrobial activity are flavonoids and polyphenols (phenols). This research aims to formulate and test the physical stability of a shampoo combining ethanol extract of jackfruit leaves (Artocarpus heterophyllus) and pandan leaves (Pandanus Amaryllifolius) with varying carbomer concentrations. This research method is laboratory experimental. The carbomer concentration used is 0.1%, 0.3%, 0.5%. The research results showed that the shampoo preparation with the best carbomer concentration was formula 3 with a carbomer concentration of 0.5%. Viewed from an organoleptic perspective, namely with a blackish brown color, the typical smell of pandan accompanied by menthol, pH 6, the shampoo preparation obtained is homogeneous and produces the best foam, namely 13.5 cm in formula 3. Keywords: Shampoo, anti-dandruff, pandan leaves, jackfruit leaf extract.
头发对人类来说扮演着重要的角色,因为头发可以影响一个人的外表。蒲丹叶(Pandanus Amaryllifolius)含有生物碱、黄酮类、皂苷、多酚、单宁和染料等形式的化合物。在板蓝根叶中,能提供抗菌活性的化合物是类黄酮和多酚(酚)。本研究旨在配制和测试一种洗发水的物理稳定性,该洗发水结合了胡柚叶(Artocarpus heterophyllus)和板丹叶(Pandanus Amaryllifolius)的乙醇提取物以及不同浓度的卡波姆。该研究方法为实验室实验法。使用的卡波姆浓度分别为 0.1%、0.3% 和 0.5%。研究结果表明,卡波姆浓度最佳的洗发水制剂是卡波姆浓度为 0.5%的配方 3。从感官角度来看,配方 3 的洗发水呈黑褐色,有典型的丹皮味,伴有薄荷醇,pH 值为 6,配方 3 的洗发水质地均匀,产生的泡沫最好,为 13.5 厘米。关键词洗发水、去屑、丹参叶、柚子叶提取物。
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引用次数: 0
Synthesis and Characterization of Hexathiosianatoiron(II) [Fe(NCS)6] 4- Complex Compound and Tetrapyridindithiosianatoiron(II) [Fe(NCS)2(Py)4] Complex Compound 六硫代二锍铁(II)[Fe(NCS)6] 4-络合物和四吡啶靛基二锍铁(II)[Fe(NCS)2(Py)4] 络合物的合成与表征
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56440
Fitria Febrianti, A. Sutiani, I. Jahro, A. Nugraha, Nabila Nur Fadhila
This research aims to synthesize and characterize the complex compounds Hexathiocyanatoiron(II) [Fe(NCS)6] 4- and Tetrapyridinedithiocyanatoiron(II) [Fe(NCS)2(Py)4]. The synthesis of these complex compounds was conducted in the Chemistry Laboratory, Faculty of Mathematics and Natural Sciences, Medan State University, while magnetic susceptibility measurements were carried out using the Magnetic Susceptibility Balance (MSB) instrument in the Inorganic Chemistry Laboratory, Bandung Institute of Technology. The complex compound synthesis involved the reaction of Iron(II) sulfate heptahydrate with Potassium thiocyanate and Pyridine compound in a 1:2 and 1:2:4 molar ratio. The synthesis process was conducted through a direct reaction method in a polar solvent. The obtained results include Hexathiocyanatoiron(II) complex compound, [Fe(NCS)6] 4-, which is pale yellow crystalline with a yield of 32.76%, and Tetrapyridinedithiocyanatoiron(II) complex compound, [Fe(NCS)2(Py)4] which is dark purple crystalline with a yield of 52.62%. These compounds exhibit a melting point of 219℃. Magnetic susceptibility measurements using the MSB instrument revealed a magnetic susceptibility of 6.69 BM (paramagnetic) for the Hexathiocyanatoiron(II) complex[Fe(NCS)6] 4-, and a magnetic moment of 5.61 BM (diamagnetic) for the Tetrapyridinedithiocyanatoiron(II ) complex [Fe(NCS)2(Py)4].
本研究旨在合成六硫氰基铁(II)[Fe(NCS)6] 4- 和四吡啶二硫氰基铁(II)[Fe(NCS)2(Py)4] 复合物,并对其进行表征。这些复合物的合成是在棉兰国立大学数学与自然科学学院化学实验室进行的,而磁感应强度测量则是在万隆理工学院无机化学实验室使用磁感应强度天平(MSB)仪器进行的。复合物合成涉及硫酸铁(II)七水合物与硫氰酸钾和吡啶化合物按 1:2 和 1:2:4 的摩尔比进行反应。合成过程是在极性溶剂中通过直接反应法进行的。合成结果包括六硫氰酸铁(II)络合物[Fe(NCS)6] 4- 和四吡啶二硫氰酸铁(II)络合物[Fe(NCS)2(Py)4],前者为淡黄色结晶,收率为 32.76%,后者为深紫色结晶,收率为 52.62%。这些化合物的熔点为 219℃。使用 MSB 仪器进行的磁感应强度测量显示,六硫氰酸铁(II)络合物[Fe(NCS)6] 4- 的磁感应强度为 6.69 BM(顺磁性),而四吡啶二硫氰酸铁(II)络合物[Fe(NCS)2(Py)4]的磁矩为 5.61 BM(二磁性)。
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引用次数: 0
Synthesis and Characterization of Activated Carbon/Alginate-Fe Composites as Slow Release Fertilizer 作为缓释肥料的活性炭/海藻酸铁复合材料的合成与表征
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56450
Teguh Hidayat Panjaitan, Z. Muchtar, Siti Rahmah, M. Zubir, Ahmad Shafwan Pulungan, R. Selly, P. Faradilla
Research on the slow release kinetics of Fe(III) ions from Activated Carbon/Alginate-Fe(III) composites or abbreviated as K/A-Fe(III) has been carried out. The aim of this research was to synthesize K/A-Fe(III) composite as a material that has the potential to become a slow release micronutrient fertilizer and to study the kinetics of slow release of Fe(III) ions from the composite. The K/A-Fe(III) composite was synthesized by mixing alginate suspension and activated carbon (alginate: activated carbon weight ratio = 1:3 and 3:1) until homogeneous. Composite grains were characterized using Fourier Transformed Infrared (FTIR) spectroscopy, the kinetics of Fe(III) release from the three composite variations found that KAlg31 composite showed more absorption and release of Fe ions than KAlg13.
对活性炭/海藻酸盐-铁(III)复合材料(简称 K/A-Fe(III))中铁(III)离子的缓释动力学进行了研究。这项研究的目的是合成 K/A-Fe(III) 复合材料,使其具有成为缓释微量营养元素肥料的潜力,并研究从复合材料中缓释 Fe(III) 离子的动力学。K/A-Fe(III) 复合材料是通过将海藻酸悬浮液和活性炭(海藻酸:活性炭重量比 = 1:3 和 3:1)混合至均匀而合成的。使用傅立叶变换红外光谱(FTIR)对复合材料颗粒进行了表征,从三种不同的复合材料中释放铁(III)的动力学发现,KAlg31 复合材料比 KAlg13 复合材料对铁离子的吸收和释放更多。
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引用次数: 0
Antibacterial Activity Test of Ag Nanoparticle Soap Turi Leaf Extract (Sesbania grandiflora) Against Staphylococcus aureus Bacteria 银纳米粒子皂都里叶(大戟科)提取物对金黄色葡萄球菌的抗菌活性测试
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56445
Della Ayu Rusiana, Inur Tivani
Silver metal nanoparticles have biocidal properties as a non-toxic inorganic antibacterial agent. Flavonoid compounds from the Turi Leaf (Sesbania grandiflora) plant extract as a natural bio reductant. In the research, UV-Vis spectrophotometric testing parameters and antibacterial soap preparations were carried out. Synthesis and Characteristics of Silver Nanoparticles were carried out, with soap preparations made into 3 formulas with different variations in Agno3 concentration, namely 1 mM, 2 mM, and 3 mM and antibacterial activity tested using well diffusion. The results of the absorption spectrum of Ag nanoparticles show the highest peak at a value of 280-290 nm. In the antibacterial activity test, the greater the AgNO3 concentration in the Ag nanoparticle soap, the greater the inhibition zone created by Staphylococcus aureus bacteria. The optimum concentration in soap preparations is 3 mM producing a wavelength of 300 nm with an absorbance value of 1.105. In terms of antibacterial activity, the most effective way to inhibit the growth of Staphylococcus aureus bacteria is formulation III, with an inhibitory power of 7.69 cm2 .
银金属纳米粒子作为一种无毒无机抗菌剂具有杀菌特性。从都里叶(Sesbania grandiflora)植物提取物中提取黄酮类化合物作为天然生物还原剂。研究中还进行了紫外可见分光光度测试参数和抗菌肥皂的制备。研究人员进行了银纳米粒子的合成和特性研究,将肥皂制剂制成 3 种不同浓度的 Agno3 配方,即 1 mM、2 mM 和 3 mM,并使用井扩散法测试其抗菌活性。银纳米粒子的吸收光谱结果显示,最高峰在 280-290 纳米波长处。在抗菌活性测试中,银纳米粒子肥皂中的 AgNO3 浓度越高,金黄色葡萄球菌产生的抑菌区就越大。肥皂制剂中的最佳浓度为 3 毫摩尔,波长为 300 纳米,吸光度值为 1.105。就抗菌活性而言,抑制金黄色葡萄球菌生长最有效的方法是配方 III,其抑制能力为 7.69 平方厘米。
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引用次数: 0
The Properties of Ethyl Acetate Extract of Frankincense (Styrax benzoin) Using the Maceration Method 采用浸渍法提取乳香(安息香)乙酸乙酯的特性
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56438
Nora Susanti, J. Purba, Salsabila Tambunan
This study aims to determine the standardization of ethyl acetate extract of frankincense gum using the maceration method. The method used in this study was to standardize the ethyl acetate extract of frankincense using specific and non-specific parameters. The results of standardization with specific parameters showed that the ethyl acetate extract of frankincense latex was blackish brown in color and had a distinctive odor of frankincense. It contained 86.5% soluble compound in ethanol. The results of standardization with non-specific parameters showed a specific gravity of 0.8213 g/ml and an average moisture content of 1.71%. The chemical components contained are Benzoic acid; Vanillin; transCinnamic acid; Phenol, 2-methoxy-4-propyl-; 2-Propanone, 1-(4) -hydroxy-3-methoxyphenyl)-; Benzoic acid, phenylmethyl ester; (Z)-Cinnamyl benzoate; 2-Propenoic acid, 3-phenyl-,phenylmethyl ester, (E) -; and Cinnamyl cinnamate.
本研究旨在利用浸渍法确定乳香树胶乙酸乙酯提取物的标准化。本研究采用的方法是使用特定和非特定参数对乳香乙酸乙酯提取物进行标准化。用特定参数进行标准化的结果显示,乳香胶的乙酸乙酯提取物呈黑褐色,具有乳香的独特气味。乙醇中含有 86.5% 的可溶性化合物。非特异性参数标准化结果显示,比重为 0.8213 克/毫升,平均含水量为 1.71%。所含化学成分为苯甲酸;香兰素;反式肉桂酸;苯酚,2-甲氧基-4-丙基-;2-丙酮,1-(4)-羟基-3-甲氧基苯基)-;苯甲酸,苯基甲酯;(Z)-肉桂醇苯甲酸酯;2-丙烯酸,3-苯基,苯基甲酯,(E)-;肉桂醇肉桂酸酯。
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引用次数: 0
Effect of Contact Time and Stirring Speed on Biosorption of Lead (II) Using Sugarcane Bagasse 接触时间和搅拌速度对甘蔗渣生物吸附铅 (II) 的影响
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56443
Nur Rizky Pasaribu, D. Kurniawati
Lead is a hazardous and toxic metal if it reaches human organs in sufficient doses or if it is present in water. Pb2+ can build up in the brain, causing cancer, disorders of nerve cells, kidneys and mental health as well as problems with male reproduction and resulting in bone irregularities in children. As a result, it is vital to regulate the presence of this metal in water. Biosorption is a heavy metal removal technique that use biomass as an adsorbent. The biosorption method was conducted in this study employing sugarcane bagasse as an adsorbent and batch contacting. Variations in contact duration and stirring speed were tested in this study to determine the influence of contact time and stirring speed on the biosorption process. The study's findings revealed that a contact duration of 60 minutes and a stirring speed of 100 rpm were the best conditions in this research.
如果铅进入人体器官的剂量足够大,或者铅存在于水中,那么铅就是一种有害的有毒金属。Pb2+ 可在大脑中积聚,导致癌症、神经细胞紊乱、肾脏和精神健康问题,以及男性生殖问题,并导致儿童骨骼发育不全。因此,调节这种金属在水中的含量至关重要。生物吸附是一种使用生物质作为吸附剂的重金属去除技术。本研究采用甘蔗渣作为吸附剂,采用批量接触法进行生物吸附。本研究测试了接触时间和搅拌速度的变化,以确定接触时间和搅拌速度对生物吸附过程的影响。研究结果表明,60 分钟的接触时间和 100 转/分钟的搅拌速度是本研究的最佳条件。
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引用次数: 0
GCMS Analysis of Bakong Gayo or Gayo Tobacco (Nicotiana tabacum L) Leaves Extract and Pharmaceutical Uses Bakong Gayo 或 Gayo 烟草(Nicotiana tabacum L)叶提取物的 GCMS 分析及其制药用途
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56451
Supiyani Supiyani, Saisa Saisa
Tobacco plants are considered more destructive plants than medicinal plants. This research aims to analyze using GCMS (gas chromatography mass spectrometry) the leaves extract of Bakong Gayo or Gayo tobacco (Nicotiana tabacum L) and its pharmaceutical uses. Extraction of Gayo tobacco leaves with chloroform solvent obtained 14 phytochemical compounds in the form of alkaloids, terpenoids and fatty acids. The phytochemical compounds in Gayo tobacco can be used as antibacterial, anticancer, anti-depressant, antioxidant, sedative, aromatherapy based on references and other potential to be developed as a medicinal plant.
烟草被认为是比药用植物更具破坏性的植物。本研究旨在使用 GCMS(气相色谱质谱法)分析 Bakong Gayo 或 Gayo 烟草(Nicotiana tabacum L)的叶片提取物及其制药用途。用氯仿溶剂萃取 Gayo 烟草叶片可获得 14 种生物碱、萜类和脂肪酸形式的植物化学物质。根据参考文献,加约烟草中的植物化学物质可用于抗菌、抗癌、抗抑郁、抗氧化、镇静、芳香疗法,并具有作为药用植物开发的其他潜力。
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引用次数: 0
Physical Characteristics And Phytochemical Screeningfrom Oil And Red Fruit Juice (Pandanus Conoideus L.) 油和红色果汁的物理特征和植物化学筛选(Pandanus Conoideus L.)
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56449
Wasilatul Aulia, Rizki Febriyanti, Wilda Amananti
Red Fruit Oil contains several active compounds that are beneficial for the human body such are tocopherol, betacarotene and some types of fatty acids such as oleic acid, linoleic acid, linolenic acid and decanoic. The purpose of this study was to determine the content of secondary metabolites in oil and red fruit juice (Pandanus conoideus). This research method uses qualitative data research methods, namely from the results of analysis of the content of secondary metabolites of oil and Red Fruit juice (Pandanus conoideus) consisting of alkaloids, flavonoids, terpenoids, saponins and tannins, as well as thin-layer chromatography. The results of the study showed that phytochemical screening tests of red fruit oil and red fruit juice hand products gave the same results as red fruit oil (brand x) on the market, that the three samples contained several secondary metabolite compounds namely flavonoids, tannins, and terpenoids
红果油含有多种对人体有益的活性化合物,如生育酚、β-胡萝卜素和某些类型的脂肪酸,如油酸、亚油酸、亚麻酸和癸酸。本研究的目的是确定油和红色果汁(露兜树)中次生代谢物的含量。本研究方法采用定性数据研究方法,即从油和红果汁(Pandanus conoideus)中由生物碱、黄酮类、萜类、皂苷和单宁组成的次生代谢物含量分析结果,以及薄层色谱法。研究结果表明,红果油和红果汁手工产品的植物化学筛选测试结果与市场上的红果油(品牌 x)相同,三个样本含有多种次级代谢化合物,即黄酮类、单宁酸和萜类化合物。
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引用次数: 0
Potential Analysis of Quercetin and Its Derivatives as Inhibitors of Hendra Virus (HeV) 槲皮素及其衍生物作为亨德拉病毒(HeV)抑制剂的潜力分析
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56448
Nur Anisa Rosyiidah, P. Setiarso, Gusti Made Sanjaya
This study aims to determine the inhibitory potential of quercetin and its derivatives on the activity of Hendra virus (HeV) 6BK6 protein with its comparator N-Acetyl-D-[1-13C] Glucosamine. This research was carried out using the molecular docking method in order to obtain information related to binding affinity values, inhibition constants, and amino acid residues in the ligand-receptor hydrogen bonds. It was found that the compound quercetin 3-O-xyloside had the lowest binding affinity among the other compounds, namely -6.92 kcal/mol with an inhibition constant of 8.44 µM. In addition, there are four types of amino acid residues in the ligand-receptor hydrogen bonds including ASP304 (1,90 Å), SER301 (2,47 Å), ARG191 (3,18 Å), and MET188 (4.34 Å). In this case it can be concluded that the compound quercetin 3-O-xyloside has been shown to have the potential to inhibit the activity of the HeV 6BK6 protein.
本研究旨在确定槲皮素及其衍生物对与之比较的 N-乙酰基-D-[1-13C] 葡萄糖胺的亨德拉病毒(HeV)6BK6 蛋白活性的抑制潜力。该研究采用分子对接方法,以获得与配体-受体氢键的结合亲和值、抑制常数和氨基酸残基有关的信息。结果发现,槲皮素-3-O-木糖苷化合物的结合亲和力在其他化合物中最低,为-6.92 kcal/mol,抑制常数为 8.44 µM。此外,配体-受体氢键中有四种氨基酸残基,包括 ASP304(1.90 Å)、SER301(2.47 Å)、ARG191(3.18 Å)和 MET188(4.34 Å)。由此可以得出结论,化合物槲皮素 3-O-xyloside 具有抑制 HeV 6BK6 蛋白活性的潜力。
{"title":"Potential Analysis of Quercetin and Its Derivatives as Inhibitors of Hendra Virus (HeV)","authors":"Nur Anisa Rosyiidah, P. Setiarso, Gusti Made Sanjaya","doi":"10.24114/ijcst.v7i1.56448","DOIUrl":"https://doi.org/10.24114/ijcst.v7i1.56448","url":null,"abstract":"This study aims to determine the inhibitory potential of quercetin and its derivatives on the activity of Hendra virus (HeV) 6BK6 protein with its comparator N-Acetyl-D-[1-13C] Glucosamine. This research was carried out using the molecular docking method in order to obtain information related to binding affinity values, inhibition constants, and amino acid residues in the ligand-receptor hydrogen bonds. It was found that the compound quercetin 3-O-xyloside had the lowest binding affinity among the other compounds, namely -6.92 kcal/mol with an inhibition constant of 8.44 µM. In addition, there are four types of amino acid residues in the ligand-receptor hydrogen bonds including ASP304 (1,90 Å), SER301 (2,47 Å), ARG191 (3,18 Å), and MET188 (4.34 Å). In this case it can be concluded that the compound quercetin 3-O-xyloside has been shown to have the potential to inhibit the activity of the HeV 6BK6 protein.","PeriodicalId":13519,"journal":{"name":"Indonesian Journal of Chemical Science and Technology (IJCST)","volume":"53 24","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140085945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Indonesian Journal of Chemical Science and Technology (IJCST)
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