Preparation of Metal - Organic Framework MIL-88B(Fe)-NH2 for Efficient Adsorption of Congo Red in Aqueous Environment

Hoang Thi Linh Giang, Dang Thi Minh Hue, Tran Thi Luyen, Tran Vinh Hoang, Huynh Dang Chinh
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Abstract

MIL-88B(Fe)-NH2 material was prepared by a simple solvothermal method. Various techniques were performed to investigate material characteristics including X-ray diffraction (XRD), scanning electron spectroscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) surface area. The result indicates that the particle shape is a bipyramidal hexagonal prism having a porous surface, and the BET surface area is 13.43 m2/g. Adsorption of congo red (CR) onto MIL-88B(Fe)-NH2 was studied as well. The adsorption equilibrium of the material is reached rapidly after 10 minutes with excellent adsorption efficiency (98.02%). Adsorption kinetic conforms to Langmuir isothermal adsorption model with the high maximum capacity of 333.33 mg/g.
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制备用于在水环境中高效吸附刚果红的金属有机框架 MIL-88B(Fe)-NH2
MIL-88B(Fe)-NH2 材料是通过简单的溶热法制备的。对材料特性进行了多种技术研究,包括 X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、透射电子显微镜 (TEM) 和布鲁诺-艾美特-泰勒 (BET) 表面积。结果表明,颗粒形状为双锥六方棱柱,表面多孔,BET 表面积为 13.43 m2/g。此外,还研究了 MIL-88B(Fe)-NH2 对刚果红(CR)的吸附情况。材料在 10 分钟后迅速达到吸附平衡,吸附效率极高(98.02%)。吸附动力学符合 Langmuir 等温吸附模型,最大吸附容量高达 333.33 mg/g。
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