Expanded perlite mineral as a natural additive used in polylactide-based biodegradable composites

Erkan Aksoy, Süha Tirkeş, Ümit Tayfun, S. Tirkeş
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Abstract

Polylactide (PLA) is a biodegradable polymer derived from natural resources used in various applications ranging from medical to packaging. In this study, biocomposites were developed by combining perlite mineral (PER), a natural filler material, with a biodegradable PLA matrix in incorporated contaminations of 2.5%, 5%, 10%, and 15%. Mixing force measurements, tensile, Shore hardness, impact tests, melt flow indices (MFI), and scanning electron microscopy (SEM) evaluations were carried out on composite samples to determine the processing, mechanical, melt flow, and morphological aspects of the developed composites. When the tensile test data were reviewed, minor decreases in the tensile strength and % elongation parameters were noticed with perlite loadings. The inclusion of perlite powder significantly reduced the impact strength value of PLA. Composites with high amounts of PER displayed elevated hardness values. While the MFI results were analyzed, it was discovered that the addition of PER increased the melt flow characteristics of the PLA polymer. At low PER quantities, SEM micrographs revealed that PER particles were homogeneously distributed in the PLA phase. The particle homogeneity in the composite morphology deteriorated as the PER loading ratio in the composites rose. According to the overall results, the highest performance among composites was achieved in the sample including 2.5% PER, and this sample was considered to be the most suitable option for applications regarding PLA-based biocomposite material purposes.
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膨胀珍珠岩矿物作为天然添加剂用于聚乳酸基生物可降解复合材料
聚乳酸(PLA)是一种从自然资源中提取的可生物降解聚合物,可用于从医疗到包装等各种领域。在这项研究中,通过将天然填充材料珍珠岩矿物(PER)与可生物降解的聚乳酸基体相结合,开发出了生物复合材料,其掺入量分别为 2.5%、5%、10% 和 15%。对复合材料样品进行了混合力测量、拉伸、肖氏硬度、冲击试验、熔体流动指数(MFI)和扫描电子显微镜(SEM)评估,以确定所开发复合材料的加工、机械、熔体流动和形态等方面。拉伸测试数据显示,随着珍珠岩含量的增加,拉伸强度和伸长率参数略有下降。珍珠岩粉末的加入大大降低了聚乳酸的冲击强度值。含有大量 PER 的复合材料显示出较高的硬度值。在对 MFI 结果进行分析时发现,添加 PER 增加了聚乳酸聚合物的熔体流动特性。在低 PER 量时,SEM 显微照片显示 PER 颗粒均匀地分布在聚乳酸相中。随着 PER 在复合材料中添加比例的增加,复合材料形貌中的颗粒均匀性有所下降。从总体结果来看,PER 含量为 2.5% 的样品的复合材料性能最高,因此该样品被认为是最适合应用于聚乳酸基生物复合材料的样品。
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