RECEIVING METALS FROM SECONDARY RAW MATERIALS. POWDER OF SILVER

D. G. Korolyanchuk, V.I. Ovcharenko
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Abstract

Purpose of research. Powder of silver is one of the most widely used materials in industry. In the free or sintered (compressed) state, it is widely used in medicine as an element of antiseptics, in electronics as the basis of conductive pastes, conductive adhesives and contacts intended for closing and opening electrical circuits, in the production of multilayer ceramic capacitors, etc. Due to its high electrical conductivity, powder of silver is also used as a cathode material in solar cells. In today's conditions, the development of materials for alternative energy sources is quite relevant. Powder of silver can be used as a component of the active mass in chemical current sources. It is known that the characteristics of the active mass are influenced by the properties of the powder, namely, the size and shape of the particles. Materials and methodology. In this work, it was proposed to use boards of radio-electronic equipment as raw materials for the production of powders of silver. The reductant, recovery rate and modes of obtaining finely dispersed powders of silver after processing of secondary raw materials were identified. Results. The influence of the parameters of the reduction of powders of silver, namely, the type of reducing agent and the rate of reduction, was studied. It was established that in the process of forming powders of silver, a developed morphology and space between particles are formed, which increases the surface area, due to which the performance characteristics of various devices, in which powder of silver can be used as a component, will improve. Scientific novelty. Factors that affect the size and shape of powder of silver particles, namely, the type of reducing agent and the rate of reduction, have been established. Conclusions. It was established that the size of particles of silver depends on the speed of recovery. The stronger the reducing agent, the higher the rate of metal reduction, and the larger the particle size. Changing the speed of recovery (slowing down or speeding up) allows you to get particles of silver with the desired size. The indisputable advantage of the method of obtaining powder of silver by reduction is the formation of high-purity metal, which positively affects the properties.
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从二次原材料中获取金属。银粉
研究目的。银粉是工业中使用最广泛的材料之一。在自由或烧结(压缩)状态下,银粉被广泛应用于医药领域,作为防腐剂的一种成分;在电子领域,银粉被用作导电浆料、导电粘合剂和用于闭合和打开电路的触点的基础;在多层陶瓷电容器的生产中,银粉也被广泛应用。由于银粉具有高导电性,它还被用作太阳能电池的阴极材料。在当今条件下,替代能源材料的开发具有重要意义。银粉可用作化学电流源的活性物质成分。众所周知,活性物质的特性受粉末特性的影响,即颗粒的大小和形状。材料和方法。在这项工作中,建议使用无线电电子设备的电路板作为生产银粉的原材料。确定了二次原材料加工后的还原剂、回收率和获得精细分散银粉的模式。研究结果研究了银粉还原参数,即还原剂类型和还原率的影响。结果表明,在形成银粉的过程中,颗粒之间形成了发达的形态和空间,从而增大了表面积,由于表面积的增大,可以使用银粉作为部件的各种设备的性能特征将得到改善。科学新颖性。确定了影响银粉颗粒大小和形状的因素,即还原剂的类型和还原速度。结论。已确定银颗粒的大小取决于还原速度。还原剂越强,金属还原率越高,颗粒尺寸越大。改变回收速度(减慢或加快)可以获得所需的银颗粒大小。通过还原获得银粉的方法无可争议的优点是形成高纯度金属,这对其性能有积极影响。
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