The Extraction of Chitin from Indonesian Shells and its Potential as Zinc Ion Batteries Supporting Material

Abdillah Syah Putra, Irma Sulistina, Mutiara Febrianti, Nuril Mina Apdhila, C. Yudha
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Abstract

Indonesia is an archipelagic country that has a very wide water area. One of the results of aquaculture in Indonesia is shrimp. Shrimp production results based on data from the Ministry of Maritime Affairs and Fisheries in 2022 amounted to 8,3 tons. This makes Indonesia one of the largest shrimp-exporting countries in Southeast Asia. The part of the shrimp that is often consumed by the public is the meat. So that the heads, tails, and shells that have been peeled are often discarded. Shrimp waste besides being able to pollute the environment can also disturb the comfort of local residents, so efforts are needed to overcome it. Shrimp shell contains 27.6% minerals, 34.9% protein, and 18.1% chitin. The chitin content in shrimp shells can be processed into materials for zinc-ion batteries, namely into chitosan which has non-toxic properties and can be used as polymer electrolytes that have good conductivity values through the deacetylation process. The main ingredient used is shrimp shell powder from shrimp waste that has been cleaned and dried. In this study, there are three steps of procedures, namely the deproteination method using NaOH base solution, demineralization using HCl acid solution, and testing for the presence of chitin with the Van Wesslink color reaction. In this experiment, the yields obtained were 0.38, 0.1, 0.12, dan 0.47-gram chitin/gram shrimp shell. The big difference in the yield produced is due to the different types of shrimp waste used.
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从印度尼西亚贝壳中提取甲壳素及其作为锌离子电池的潜力 佐证材料
印度尼西亚是一个群岛国家,水域面积非常广阔。对虾是印尼水产养殖的成果之一。根据海洋事务和渔业部的数据,2022 年的对虾产量为 8.3 吨。这使印尼成为东南亚最大的对虾出口国之一。公众经常食用的部分是虾肉。因此,虾头、虾尾和剥掉的虾壳通常会被丢弃。虾的废弃物除了会污染环境外,还会影响当地居民的生活舒适度,因此需要努力加以克服。虾壳含有 27.6% 的矿物质、34.9% 的蛋白质和 18.1% 的甲壳素。虾壳中的甲壳素可以加工成锌离子电池的材料,即甲壳素,它具有无毒的特性,通过脱乙酰化过程可用作具有良好导电值的聚合物电解质。使用的主要成分是虾壳粉,虾壳粉来自经过清洗和干燥的虾类废弃物。在这项研究中,有三个步骤,即使用 NaOH 碱溶液进行脱乙酰化法,使用 HCl 酸溶液进行脱矿物质法,以及使用 Van Wesslink 颜色反应检测甲壳素的存在。在该实验中,甲壳素的产量分别为 0.38、0.1、0.12 和 0.47 克/克虾壳。产率的巨大差异是由于使用了不同种类的虾废料。
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