Pub Date : 2024-02-06DOI: 10.20961/esta.v3i1.78985
Tika Paramitha
Electronic waste in Indonesia continues to increase, electronic waste is categorized as B3 waste which can threaten the environment. Electronic waste contains metals that can berecovery namely 20% copper (Cu), 8% iron (Fe), 4% tin (Sn), 2% nickel (Ni), 2% lead (Pb), 1% zinc (Zn), 0.2% silver (Ag), 0.1% gold (Au) and 0.005% palladium (Pa). Copper can be used as a raw material for making pigments mountain blue. Pigment extraction from copper metal can be done using the hydrometallurgical method which is considered more environmentally friendly and economical. The hydrometallurgical method uses solvents in the liquid phase to dissolve copper metal from waste and convert it into the desired compound. The materials used to make mountain blue pigment are copper waste, sulfuric acid (H2SO4), sodium hydroxide (NaOH), sodium carbonate (Na2CO3), hydrogen peroxide (H2O2), and distilled water. Meanwhile, the materials used for pigment application are Carboxymethyl Cellulose (CMC) and titanium dioxide (TiO2). In this process, washing or leaching will be carried out(leaching) namely a chemical concentration process to release ore impurities from a mineral by dissolving it using certain reagents. Factors that influence the metal leaching process are temperature and acid concentration. In this experiment, the hydrometallurgical method succeeded in processing electronic waste into a blue pigment (mountain blue). The average pigment yield mountain blue in this experiment it was 1.25 grams of montain blue/gram of copper. Furthermore, the average conversion of pigment mountain blue was 89.3%.
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Pub Date : 2024-02-06DOI: 10.20961/esta.v3i1.73900
Agus Purwanto, Annisa Salsabila Ghina Muthi, Ardian Febrianto, Muhammad Nur Ikhsanuddin
Inside battery, the electrolyte becomes a very important electrochemical device. The electrolyte functions as a transfer medium for Li ions in the battery. One of the salts that can cover the deficiency of LiPF6 as an electrolyte material that is currently widely used is LiBOB ( Lithium BisBorate ) salt material. Lithium bis (oxalato) borate material is a new lithium salt which was first introduced in 1999 by Xu et al [4], which is currently being developed as a replacement electrolyte for lithium ion batteries. LiBOB is a promising electrolyte material regarding battery safety since judging from the potential for excess salt supported by previous research, LiBOB can be the answer to the problem of using electrolytes that are not environmentally friendly. The synthesis of LiBOB refers to Wigayati (2018) ×