The Influence of Freezing-thawing on the Properties of Sludge from Water Treatment Facilities and the Prospects for its Disposal

M. Belkanova, V. Avdin, D. M. Galimov
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Abstract

It has been shown that the freezing-thawing method allows a sharp increase in the water-yielding capacity of water treatment sludge (WTS sludge) and leads to an increase in the median particle size of the dispersed phase of sludge. The distribution of bound water types in WTP sludge was studied using thermogravimetry (TG), differential thermal thermogravimetry (DTG), differential scanning calorimetry (DSC) and mass spectrometry of gaseous thermolysis products (MS). It has been established that the release of water and carbon dioxide is completely completed at a temperature of 600°C. The specific surface area of the solid phase of WTP sludge before and after freezing-thawing was determined. The pore size distribution was studied. The BET isotherm of WTP sludge corresponds to mesoporous sorbents.
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冻融对水处理设施污泥性质的影响及其处置前景
研究表明,冻融法可使水处理污泥(WTS 污泥)的产水量急剧增加,并导致污泥分散相的中值粒径增大。利用热重仪(TG)、差热分析法(DTG)、差示扫描量热法(DSC)和气态热解产物质谱法(MS)对水处理污泥中结合水类型的分布进行了研究。结果表明,水和二氧化碳在 600°C 的温度下完全释放。测定了冻融前后 WTP 污泥固相的比表面积。对孔径分布进行了研究。WTP 污泥的 BET 等温线与介孔吸附剂相对应。
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