Unraveling the potential of heteroanionic titanium oxycarbide photocatalysts for detoxifying SARS-Cov-2 antigen rapid test kit reagent solution in water sources

Abstract

In the last few years, the COVID-19 pandemic has increased the usage of antigen rapid test (ART) kits and improper disposal of these kits has led to the mixing of toxic chemical compounds present in the ART reagent solution container into drinking water sources. When consumed with drinking water, these compounds can be harmful and toxic to both humans and aquatic life. Therefore, this research presents a study on the photocatalytic degradation of the Antigen Rapid Test-Reagent solution (ART-RS) using a single-phase titanium oxycarbide - TiO_0.25 C_0.75 (TiOC) photocatalyst synthesized through a solid-state reaction. The synthesized samples were studied using various characterization tools to analyze their structural, morphological, and optical characteristics. In the photocatalytic experiment, it was found that the synthesized titanium oxycarbide photocatalyst exhibited superior ART-RS degradation efficiency of 77% compared to commercial titanium dioxide (22%). The improved photocatalytic degradation efficiency of ART-RS is attributed to a combination of several factors. These factors include a narrower band gap, more efficient charge transfer kinetics, enhanced absorption of visible light, and an upward shift of the valence band (VB) edge in titanium oxycarbide. These collective effects contribute to the enhanced ART-RS photocatalytic degradation activity.