首页 > 最新文献

Kuwait Journal of Science最新文献

英文 中文
Enhancing gas-quenching method for fabrication of perovskite-based photovoltaics
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-02-10 DOI: 10.1016/j.kjs.2025.100387
Afshin Hadipour
The fabrication of gas-quenched perovskite solar cells is analyzed and optimized by using different inert gases. The performance and the stability of the perovskite photovoltaic device are related to the perovskite crystallization properties, such as grain size and grain interspacing distance, as well as its impurity content and defect density. A suitable morphology of a solution-processed perovskite layer can be achieved by different routes. A promising, low cost, and large area compatible way of creating proper crystallization of the perovskite layer is gas quenching. Nitrogen gas is usually used for this purpose to flush the perovskite wet film during coating and control its nucleation stage. It is so far not clear in the literature if there is any relationship between the molecular weight of the quenching gas and the perovskite film morphology. We analyzed the crystallization properties, grain size, surface roughness, and defect density of the perovskite film and the related electrical performance and the stability of the solar cell devices, using nitrogen, helium, and argon as quenching gases. We found that the grain size of the perovskite layer can be tuned by using gases with different molecular weights. Perovskite layers quenched with helium and argon have bigger grain sizes and they are very stable under operational conditions compared to the less stable solar cell device processed by nitrogen gas with a smaller grain size.
{"title":"Enhancing gas-quenching method for fabrication of perovskite-based photovoltaics","authors":"Afshin Hadipour","doi":"10.1016/j.kjs.2025.100387","DOIUrl":"10.1016/j.kjs.2025.100387","url":null,"abstract":"<div><div>The fabrication of gas-quenched perovskite solar cells is analyzed and optimized by using different inert gases. The performance and the stability of the perovskite photovoltaic device are related to the perovskite crystallization properties, such as grain size and grain interspacing distance, as well as its impurity content and defect density. A suitable morphology of a solution-processed perovskite layer can be achieved by different routes. A promising, low cost, and large area compatible way of creating proper crystallization of the perovskite layer is gas quenching. Nitrogen gas is usually used for this purpose to flush the perovskite wet film during coating and control its nucleation stage. It is so far not clear in the literature if there is any relationship between the molecular weight of the quenching gas and the perovskite film morphology. We analyzed the crystallization properties, grain size, surface roughness, and defect density of the perovskite film and the related electrical performance and the stability of the solar cell devices, using nitrogen, helium, and argon as quenching gases. We found that the grain size of the perovskite layer can be tuned by using gases with different molecular weights. Perovskite layers quenched with helium and argon have bigger grain sizes and they are very stable under operational conditions compared to the less stable solar cell device processed by nitrogen gas with a smaller grain size.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100387"},"PeriodicalIF":1.2,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143402732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization and assessment of the metabolites from the Corrigiola telephiifolia Pourr. roots, using response surface methodology
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-02-02 DOI: 10.1016/j.kjs.2025.100383
Wissal El Yaagoubi , Smail Aazza , Meriem Soussi , Saadia Belmalha , Amal Alotaibi , Salah-Eddine Laasli , Rachid Lahlali , Lahsen El Ghadraoui
Corrigiola telephiifolia Pourr. is recognized for its health-promoting effects due to its rich bioactive compound content, particularly antioxidants. This study aimed to optimize the extraction of phenolic compounds from dried C. telephiifolia roots using various solvent combinations. A centroid simplex statistical approach was employed to evaluate the impact of different organic solvents—methanol, ethanol, and water—on extraction efficiency. The results indicated that a 50% methanol and 50% water binary combination yielded the highest total phenolic content, while an equal combination of methanol, ethanol, and water maximized total flavonoid content. Additionally, the hydromethanolic extract (50%, 50%) demonstrated the optimum antioxidant activity, with specific solvent mixtures enhancing DPPH scavenging activity and FRAP values. The optimized solvent proportions for total antioxidant capacity were 60.8% water, 30.3% ethanol, and 8.9% methanol. These findings suggest that the optimized extraction models are cost-effective and efficient, providing a valuable method for extracting high-quality phytocompounds.
{"title":"Optimization and assessment of the metabolites from the Corrigiola telephiifolia Pourr. roots, using response surface methodology","authors":"Wissal El Yaagoubi ,&nbsp;Smail Aazza ,&nbsp;Meriem Soussi ,&nbsp;Saadia Belmalha ,&nbsp;Amal Alotaibi ,&nbsp;Salah-Eddine Laasli ,&nbsp;Rachid Lahlali ,&nbsp;Lahsen El Ghadraoui","doi":"10.1016/j.kjs.2025.100383","DOIUrl":"10.1016/j.kjs.2025.100383","url":null,"abstract":"<div><div><em>Corrigiola telephiifolia Pourr.</em> is recognized for its health-promoting effects due to its rich bioactive compound content, particularly antioxidants. This study aimed to optimize the extraction of phenolic compounds from dried <em>C. telephiifolia</em> roots using various solvent combinations. A centroid simplex statistical approach was employed to evaluate the impact of different organic solvents—methanol, ethanol, and water—on extraction efficiency. The results indicated that a 50% methanol and 50% water binary combination yielded the highest total phenolic content, while an equal combination of methanol, ethanol, and water maximized total flavonoid content. Additionally, the hydromethanolic extract (50%, 50%) demonstrated the optimum antioxidant activity, with specific solvent mixtures enhancing DPPH scavenging activity and FRAP values. The optimized solvent proportions for total antioxidant capacity were 60.8% water, 30.3% ethanol, and 8.9% methanol. These findings suggest that the optimized extraction models are cost-effective and efficient, providing a valuable method for extracting high-quality phytocompounds.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100383"},"PeriodicalIF":1.2,"publicationDate":"2025-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143388262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review on multi-therapeutic potential of the Mitragyna speciosa (kratom) alkaloids mitragynine and 7-hydroxymitragynine: Experimental evidence and future perspectives
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-25 DOI: 10.1016/j.kjs.2025.100381
Taslima Begum , Mohd Hafiz Arzmi , Murni Nazira Sarian , Syed Adnan Ali Shah , Syed Najmul Hejaz Azmi , ABM Helal Uddin , Alfi Khatib , Qamar Uddin Ahmed
Mitragyna speciosa (kratom) is a traditional medicinal plant of Southeast Asia, known for its pharmacologically active alkaloids, mitragynine and 7-hydroxymitragynine. The chemistry, isolation, pharmacological properties, and toxicities of these two compounds have been studied by a wide range of scientific studies. However, thus far, there is no comprehensive review of mitragynine, 7-hydroxymitragynine, and their related compounds. Therefore, this review analyzed 150 papers from PubMed®, ScienceDirect, and Google Scholar to provide information on the chemistry, method of synthesis and extraction, biological effects, and toxicities of mitragynine and 7-hydroxymitragynine. Additionally, the existing research gaps were identified and recommendations for future research were provided. It was observed that most studies focused on Mitragyna speciosa leaves, with little to no research conducted on other parts of the plant, particularly the flowers. Furthermore, there is still a lack of less costly and time-consuming protocols to obtain the two major alkaloids from different parts of the plant. Finally, most studies have focused on these two alkaloids to explore their pharmacological effects, although some studies have shown that other alkaloids exhibit better pharmacological activity.
{"title":"A review on multi-therapeutic potential of the Mitragyna speciosa (kratom) alkaloids mitragynine and 7-hydroxymitragynine: Experimental evidence and future perspectives","authors":"Taslima Begum ,&nbsp;Mohd Hafiz Arzmi ,&nbsp;Murni Nazira Sarian ,&nbsp;Syed Adnan Ali Shah ,&nbsp;Syed Najmul Hejaz Azmi ,&nbsp;ABM Helal Uddin ,&nbsp;Alfi Khatib ,&nbsp;Qamar Uddin Ahmed","doi":"10.1016/j.kjs.2025.100381","DOIUrl":"10.1016/j.kjs.2025.100381","url":null,"abstract":"<div><div><em>Mitragyna speciosa</em> (kratom) is a traditional medicinal plant of Southeast Asia, known for its pharmacologically active alkaloids, mitragynine and 7-hydroxymitragynine. The chemistry, isolation, pharmacological properties, and toxicities of these two compounds have been studied by a wide range of scientific studies. However, thus far, there is no comprehensive review of mitragynine, 7-hydroxymitragynine, and their related compounds. Therefore, this review analyzed 150 papers from PubMed®, ScienceDirect, and Google Scholar to provide information on the chemistry, method of synthesis and extraction, biological effects, and toxicities of mitragynine and 7-hydroxymitragynine. Additionally, the existing research gaps were identified and recommendations for future research were provided. It was observed that most studies focused on <em>Mitragyna speciosa</em> leaves, with little to no research conducted on other parts of the plant, particularly the flowers. Furthermore, there is still a lack of less costly and time-consuming protocols to obtain the two major alkaloids from different parts of the plant. Finally, most studies have focused on these two alkaloids to explore their pharmacological effects, although some studies have shown that other alkaloids exhibit better pharmacological activity.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100381"},"PeriodicalIF":1.2,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential effectiveness of Morchella conica and Morchella esculenta extracts against carbapenem resistant Acinetobacter baumannii
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-24 DOI: 10.1016/j.kjs.2025.100380
Faiz Ul Haq , Muhammad Imran , Sidrah Saleem , Usman Aftab , Özge Süfer , Muhsin Jamal , Fatema Gaffar
Acinetobacter baumannii is an important opportunistic bacterium causing nosocomial infections. According to the World Health Organization (WHO), A. baumannii is a top-priority bacterium for the search for novel antibacterial agents. This study was planned to assess the potential antibacterial effects of Morchella conica and Morchella esculenta against carbapenem-resistant Acinetobacter baumannii (CRAB). All the Morchella conica and Morchella esculenta extracts were analyzed for potential antibacterial activities by disk diffusion and standard broth microdilution techniques. The minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) activities of Morchella extracts against both clinical and standard American type culture collection (ATCC) strains of CRAB were noted in the current study. Furthermore, ultra-performance liquid chromatography mass spectroscopy (UPLC-MS) of both Morchella species was performed to reveal the chemical compositions of these extracts. It was observed that all M. conica extracts were able to inhibit the growth of CRAB. Both Morchella species present excellent antibacterial activity, which was comparable to tigecycline but superior to meropenem. The MIC of Morchella extracts required to completely inhibit CRAB ranged from 4.66 ± 1.7 mg/ml to 12 ± 2 mg/ml. The bactericidal effects for M. conica and M. esculenta were ≥ 8–16 mg/ml and ≥ 4–8 mg/ml, respectively. The activities of Morchella extracts against CRAB are reported for the first time. The results demonstrated Morchella extracts have the potential to inhibit CRAB growth.
{"title":"Potential effectiveness of Morchella conica and Morchella esculenta extracts against carbapenem resistant Acinetobacter baumannii","authors":"Faiz Ul Haq ,&nbsp;Muhammad Imran ,&nbsp;Sidrah Saleem ,&nbsp;Usman Aftab ,&nbsp;Özge Süfer ,&nbsp;Muhsin Jamal ,&nbsp;Fatema Gaffar","doi":"10.1016/j.kjs.2025.100380","DOIUrl":"10.1016/j.kjs.2025.100380","url":null,"abstract":"<div><div><em>Acinetobacter baumannii</em> is an important opportunistic bacterium causing nosocomial infections. According to the World Health Organization (WHO), <em>A. baumannii</em> is a top-priority bacterium for the search for novel antibacterial agents. This study was planned to assess the potential antibacterial effects of <em>Morchella conica</em> and <em>Morchella esculenta</em> against carbapenem-resistant <em>Acinetobacter baumannii</em> (CRAB). All the <em>Morchella conica</em> and <em>Morchella esculenta</em> extracts were analyzed for potential antibacterial activities by disk diffusion and standard broth microdilution techniques. The minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) activities of <em>Morchella</em> extracts against both clinical and standard American type culture collection (ATCC) strains of CRAB were noted in the current study. Furthermore, ultra-performance liquid chromatography mass spectroscopy (UPLC-MS) of both <em>Morchella</em> species was performed to reveal the chemical compositions of these extracts. It was observed that all <em>M. conica</em> extracts were able to inhibit the growth of CRAB. Both <em>Morchella</em> species present excellent antibacterial activity, which was comparable to tigecycline but superior to meropenem. The MIC of <em>Morchella</em> extracts required to completely inhibit CRAB ranged from 4.66 ± 1.7 mg/ml to 12 ± 2 mg/ml. The bactericidal effects for <em>M. conica</em> and <em>M. esculenta</em> were ≥ 8–16 mg/ml and ≥ 4–8 mg/ml, respectively. The activities of <em>Morchella</em> extracts against CRAB are reported for the first time. The results demonstrated <em>Morchella</em> extracts have the potential to inhibit CRAB growth.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100380"},"PeriodicalIF":1.2,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Occurrence and physico-chemical properties of aplite-derived kaolin from eastern Kinta valley, Malaysia
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-23 DOI: 10.1016/j.kjs.2025.100379
Ling Han Khong , Onimisi Abdullateef Jimoh , Hareyani Zabidi , Kamar Shah Ariffin
Kaolin from eastern Kinta Valley was studied for its geological, geochemical, mineralogical, and textural characteristics. Research was conducted on kaolinitic occurrence from three locations, and the samples were subjected to analysis by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), particle size distribution (PSD), X-ray fluorescence (XRF), and differential thermal analysis and thermogravimetry (DTA/TG). Field studies indicate that the aplite is originally embedded into a northwest trending fault and is kaolinized by a latter fault reactivation and hydrothermal activities related to the hydrothermal cassiterite mineralization. XRD and FTIR analyses reveal that the clays are well-ordered kaolinite and halloysite with minor illite present. Geochemically, the kaolin displays low content (<0.4%) of Fe + Ti and 0.7% alkali. The washed kaolin shows composition approaching ideal kaolin. However, the raw clay consists of a 42–77% clay fraction, with quartz as the prime coarser constituent. The clay fractions are typically soft kaolin with coarse kaolinite stacks (d50 = 7–8 μm), except for a sample with a fine halloysite fraction. This study presents a new mode of kaolin occurrence in Malaysia, with the potential to be developed into a new kaolin mining region.
{"title":"Occurrence and physico-chemical properties of aplite-derived kaolin from eastern Kinta valley, Malaysia","authors":"Ling Han Khong ,&nbsp;Onimisi Abdullateef Jimoh ,&nbsp;Hareyani Zabidi ,&nbsp;Kamar Shah Ariffin","doi":"10.1016/j.kjs.2025.100379","DOIUrl":"10.1016/j.kjs.2025.100379","url":null,"abstract":"<div><div>Kaolin from eastern Kinta Valley was studied for its geological, geochemical, mineralogical, and textural characteristics. Research was conducted on kaolinitic occurrence from three locations, and the samples were subjected to analysis by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), particle size distribution (PSD), X-ray fluorescence (XRF), and differential thermal analysis and thermogravimetry (DTA/TG). Field studies indicate that the aplite is originally embedded into a northwest trending fault and is kaolinized by a latter fault reactivation and hydrothermal activities related to the hydrothermal cassiterite mineralization. XRD and FTIR analyses reveal that the clays are well-ordered kaolinite and halloysite with minor illite present. Geochemically, the kaolin displays low content (&lt;0.4%) of Fe + Ti and 0.7% alkali. The washed kaolin shows composition approaching ideal kaolin. However, the raw clay consists of a 42–77% clay fraction, with quartz as the prime coarser constituent. The clay fractions are typically soft kaolin with coarse kaolinite stacks (d50 = 7–8 μm), except for a sample with a fine halloysite fraction. This study presents a new mode of kaolin occurrence in Malaysia, with the potential to be developed into a new kaolin mining region.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100379"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization, antioxidant, and antimicrobial activity of two sage species' organic and aqueous extracts from Morocco's Middle Atlas
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-23 DOI: 10.1016/j.kjs.2025.100382
Souad Maache , Asmae Elghouizi , Latifa Zbadi , Najoua Soulo , Ghizlane Nouioura , Badiaa Lyoussi , Ilham Elarabi
This study quantifies phenols and flavonoids and evaluates antioxidant and antibacterial activities in extracts of Salvia officinalis (SO) and Salvia blancoana subsp. mesatlantica (SB) from Immouzzer in the Middle Atlas, Morocco. Bioactive components from both plants were extracted, and their 2,2-diphenyl-1-picrylhydrazyl (DPPH), total antioxidant capacity (TAC), and ferric reducing antioxidant power (FRAP) were assessed in aqueous and organic extracts. Both extracts exhibited high levels of bioactive substances, antioxidant activity, and antibacterial properties. The highest total phenolic content (TPC) for SO and SB was in the methanol extract. SO's methanol extract had the highest total flavonoid content (TFC), while SB's aqueous extract showed the highest TFC. The methanol extract also demonstrated the highest DPPH antioxidant activity for both SB and SO, and the highest TAC levels were in the methanol extract of SB and the aqueous extract of SO. In SO, the methanol extract exhibited the highest FRAP, while SB's highest was in the ethanol extract. Both extracts demonstrated notable inhibition, with SB's ethyl acetate extract having the largest zone against Staphylococcus aureus, and SO's ethanol extract showing strong activity against Candida albicans. The ethanolic extract from SO had the lowest MIC and MBC values against Bacillus subtilis, and the lowest MIC values for Proteus mirabilis in SB were associated with the ethanolic and ethyl acetate extracts., while the lowest MBC values for both pathogens were with the ethanolic and dichloromethane extracts. Leaf extracts from both Salvia species may serve as natural antioxidants and antimicrobials for the food and pharmaceutical industries.
{"title":"Characterization, antioxidant, and antimicrobial activity of two sage species' organic and aqueous extracts from Morocco's Middle Atlas","authors":"Souad Maache ,&nbsp;Asmae Elghouizi ,&nbsp;Latifa Zbadi ,&nbsp;Najoua Soulo ,&nbsp;Ghizlane Nouioura ,&nbsp;Badiaa Lyoussi ,&nbsp;Ilham Elarabi","doi":"10.1016/j.kjs.2025.100382","DOIUrl":"10.1016/j.kjs.2025.100382","url":null,"abstract":"<div><div>This study quantifies phenols and flavonoids and evaluates antioxidant and antibacterial activities in extracts of <em>Salvia officinalis</em> (SO) and <em>Salvia blancoana</em> subsp. <em>mesatlantica</em> (SB) from Immouzzer in the Middle Atlas, Morocco. Bioactive components from both plants were extracted, and their 2,2-diphenyl-1-picrylhydrazyl (DPPH), total antioxidant capacity (TAC), and ferric reducing antioxidant power (FRAP) were assessed in aqueous and organic extracts. Both extracts exhibited high levels of bioactive substances, antioxidant activity, and antibacterial properties. The highest total phenolic content (TPC) for SO and SB was in the methanol extract. SO's methanol extract had the highest total flavonoid content (TFC), while SB's aqueous extract showed the highest TFC. The methanol extract also demonstrated the highest DPPH antioxidant activity for both SB and SO, and the highest TAC levels were in the methanol extract of SB and the aqueous extract of SO. In SO, the methanol extract exhibited the highest FRAP, while SB's highest was in the ethanol extract. Both extracts demonstrated notable inhibition, with SB's ethyl acetate extract having the largest zone against <em>Staphylococcus aureus</em>, and SO's ethanol extract showing strong activity against <em>Candida albicans</em>. The ethanolic extract from SO had the lowest MIC and MBC values against <em>Bacillus subtilis</em>, and the lowest MIC values for <em>Proteus mirabilis</em> in SB were associated with the ethanolic and ethyl acetate extracts., while the lowest MBC values for both pathogens were with the ethanolic and dichloromethane extracts. Leaf extracts from both <em>Salvia</em> species may serve as natural antioxidants and antimicrobials for the food and pharmaceutical industries.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100382"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Helianthemum oelandicum subsp. incanum and Fumana thymifolia: Characterization of LC-ESI-QTOF-MS profiles and their biological activities based on plant parts and extraction solvents
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-21 DOI: 10.1016/j.kjs.2025.100378
Ahmet Emir , Nilofar Nilofar , Ceren Emir , Gunes Coban , Evren Yildiztugay , Gokhan Zengin
The members of the genera Helianthemum and Fumana offer great potential for ethnobotanical purposes, including gastrointestinal and reproductive problems. In the current study, we focused on the chemical profile and biological properties of Helianthemum oelandicum subsp. incanum and Fumana thymifolia extracts. The extracts from the aerial parts and roots of these plants, which were obtained using n-hexane, ethyl acetate, methanol, and water, were examined. Additionally, we determined the chemical composition of the extracts through liquid chromatography-electrospray ionization-quadrupole time-of-flight-mass spectrometry (LC-ESI-QTOF-MS) and assessed their antioxidant activity using different assays. Moreover, the study involved the evaluation of acetylcholinesterase (AChE), butrycholinesterase (BChE), tyrosinase, amylase, and glucosidase activities in all the extracts. In general, benzoic acid derivatives were the major phenolic acids in both plants. Regarding antioxidant properties. In terms of H. oelandicum subsp. incanum, the aerial part methanol extract displayed the highest TPC, as a result of the highest free radical scavenging activity (DPPH: 628.93 mg TE/g and ABTS: 910.56 mg TE/g). Concerning the inhibitory effects, among H. oelandicum subsp. incanum extracts, the ethyl acetate extract of aerial parts demonstrated the highest AChE inhibition (2.44 mg GALAE/g), with the highest value found in the n-hexane extract of the roots recorded at 2.74 mg GALAE/g. In terms of tyrosinase inhibition, the methanol extracts were more active than other extracts for both plants and their parts. Taken together, these results suggest that H. oelandicum subsp. incanum and F. thymifolia may be useful for potential applications in neuroprotection, skin, and diabetes.
{"title":"Helianthemum oelandicum subsp. incanum and Fumana thymifolia: Characterization of LC-ESI-QTOF-MS profiles and their biological activities based on plant parts and extraction solvents","authors":"Ahmet Emir ,&nbsp;Nilofar Nilofar ,&nbsp;Ceren Emir ,&nbsp;Gunes Coban ,&nbsp;Evren Yildiztugay ,&nbsp;Gokhan Zengin","doi":"10.1016/j.kjs.2025.100378","DOIUrl":"10.1016/j.kjs.2025.100378","url":null,"abstract":"<div><div>The members of the genera <em>Helianthemum</em> and <em>Fumana</em> offer great potential for ethnobotanical purposes, including gastrointestinal and reproductive problems. In the current study, we focused on the chemical profile and biological properties of <em>Helianthemum oelandicum</em> subsp. <em>incanum</em> and <em>Fumana thymifolia</em> extracts. The extracts from the aerial parts and roots of these plants, which were obtained using n-hexane, ethyl acetate, methanol, and water, were examined. Additionally, we determined the chemical composition of the extracts through liquid chromatography-electrospray ionization-quadrupole time-of-flight-mass spectrometry (LC-ESI-QTOF-MS) and assessed their antioxidant activity using different assays. Moreover, the study involved the evaluation of acetylcholinesterase (AChE), butrycholinesterase (BChE), tyrosinase, amylase, and glucosidase activities in all the extracts. In general, benzoic acid derivatives were the major phenolic acids in both plants. Regarding antioxidant properties. In terms of <em>H. oelandicum</em> subsp. <em>incanum</em>, the aerial part methanol extract displayed the highest TPC, as a result of the highest free radical scavenging activity (DPPH: 628.93 mg TE/g and ABTS: 910.56 mg TE/g). Concerning the inhibitory effects, among <em>H</em>. <em>oelandicum</em> subsp. <em>incanum</em> extracts, the ethyl acetate extract of aerial parts demonstrated the highest AChE inhibition (2.44 mg GALAE/g), with the highest value found in the n-hexane extract of the roots recorded at 2.74 mg GALAE/g. In terms of tyrosinase inhibition, the methanol extracts were more active than other extracts for both plants and their parts. Taken together, these results suggest that <em>H. oelandicum</em> subsp. <em>incanum</em> and <em>F. thymifolia</em> may be useful for potential applications in neuroprotection, skin, and diabetes.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100378"},"PeriodicalIF":1.2,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel solution behaviors for some communication equation and plasma physics equation via generalized Riccati equation mapping method
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-21 DOI: 10.1016/j.kjs.2025.100376
Weerachai Thadee , Samila Kirisri , Athassawat Kammanee , Jirawan Thepjinda , Sirasrete Phoosree
The 27 analytic solutions for the nonlinear space–time fractional low-pass electrical transmission line model and the nonlinear space–time fractional Sharma-Tasso-Olver equation were obtained using the generalized Riccati equation mapping method and the Jumarie’s Riemann–Liouville fractional derivative. The kink and periodic wave behavior solutions were the many different behavior solutions that were available for these nonlinear evolution equations. We displayed the behavior graphs in three-dimensions, two-dimensions and contour. This study’s findings demonstrate that, in comparison to several other approaches, the generalized Riccati equation mapping technique provides a wider range of solutions to these equations, which shows the behavior of the solution as a wave in a variety of formats.
{"title":"Novel solution behaviors for some communication equation and plasma physics equation via generalized Riccati equation mapping method","authors":"Weerachai Thadee ,&nbsp;Samila Kirisri ,&nbsp;Athassawat Kammanee ,&nbsp;Jirawan Thepjinda ,&nbsp;Sirasrete Phoosree","doi":"10.1016/j.kjs.2025.100376","DOIUrl":"10.1016/j.kjs.2025.100376","url":null,"abstract":"<div><div>The 27 analytic solutions for the nonlinear space–time fractional low-pass electrical transmission line model and the nonlinear space–time fractional Sharma-Tasso-Olver equation were obtained using the generalized Riccati equation mapping method and the Jumarie’s Riemann–Liouville fractional derivative. The kink and periodic wave behavior solutions were the many different behavior solutions that were available for these nonlinear evolution equations. We displayed the behavior graphs in three-dimensions, two-dimensions and contour. This study’s findings demonstrate that, in comparison to several other approaches, the generalized Riccati equation mapping technique provides a wider range of solutions to these equations, which shows the behavior of the solution as a wave in a variety of formats.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100376"},"PeriodicalIF":1.2,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A kinetic study of benzyl alcohol oxidation over Pt/C catalyst
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-17 DOI: 10.1016/j.kjs.2025.100373
Firas H. Albadran , Muhammad Saeed , Ibtisam Kamal
The synthesis of carbonyl compounds by oxidation of alcohols is an important research area. A Pt/C catalyst was prepared by wet impregnation technique followed by characterization using X-ray diffraction, Fourier transform infrared spectroscopy as well as surface area and pore size analysis. It was then employed as catalyst for benzyl alcohol oxidation. The progress of oxidation reaction was monitored using GC. The oxidation data was analyzed using the nonlinear regression method using Polymath 5.1 software to analyze reaction kinetics. The rate constant and order of reaction were calculated as 9.28 × 10−6 mol L g−1s−1and 0.447, respectively. The rate law for oxidation of benzyl alcohol was proposed as RBA=ksθBA0.442θO20.005.
{"title":"A kinetic study of benzyl alcohol oxidation over Pt/C catalyst","authors":"Firas H. Albadran ,&nbsp;Muhammad Saeed ,&nbsp;Ibtisam Kamal","doi":"10.1016/j.kjs.2025.100373","DOIUrl":"10.1016/j.kjs.2025.100373","url":null,"abstract":"<div><div>The synthesis of carbonyl compounds by oxidation of alcohols is an important research area. A Pt/C catalyst was prepared by wet impregnation technique followed by characterization using X-ray diffraction, Fourier transform infrared spectroscopy as well as surface area and pore size analysis. It was then employed as catalyst for benzyl alcohol oxidation. The progress of oxidation reaction was monitored using GC. The oxidation data was analyzed using the nonlinear regression method using Polymath 5.1 software to analyze reaction kinetics. The rate constant and order of reaction were calculated as 9.28 × 10<sup>−6</sup> mol L g<sup>−1</sup>s<sup>−1</sup>and 0.447, respectively. The rate law for oxidation of benzyl alcohol was proposed as <span><math><mrow><msub><mi>R</mi><mrow><mi>B</mi><mi>A</mi></mrow></msub><mo>=</mo><msub><mi>k</mi><mi>s</mi></msub><mspace></mspace><msubsup><mi>θ</mi><mrow><mi>B</mi><mi>A</mi></mrow><mn>0.442</mn></msubsup><msubsup><mi>θ</mi><mrow><mi>O</mi><mn>2</mn></mrow><mn>0.005</mn></msubsup><mtext>.</mtext></mrow></math></span></div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100373"},"PeriodicalIF":1.2,"publicationDate":"2025-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143166745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical range of tensor product of operators in semi-Hilbert spaces
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-01-17 DOI: 10.1016/j.kjs.2025.100370
Najla Altwaijry , Christophe Chesneau , Kais Feki , Zakaria Taki
Let A and B be two positive bounded linear operators acting on the complex Hilbert spaces H and K, respectively. In this paper, we study the (AB)-numerical range WAB(TS) of the tensor product TS for two bounded linear operators T and S on H and K, respectively. In the context of this work, we demonstrate that if either T is A-hyponormal or S is B-hyponormal, then WAB(TS)¯=coWA(T)¯WB(S)¯,where WA(T) and WB(S) denote the A-numerical range of T and the B-numerical range of S, respectively. Here, co() and the over-line denote the convex hull and the closure, respectively. Moreover, we provide some (AB)-numerical radius inequalities.
{"title":"Numerical range of tensor product of operators in semi-Hilbert spaces","authors":"Najla Altwaijry ,&nbsp;Christophe Chesneau ,&nbsp;Kais Feki ,&nbsp;Zakaria Taki","doi":"10.1016/j.kjs.2025.100370","DOIUrl":"10.1016/j.kjs.2025.100370","url":null,"abstract":"<div><div>Let <span><math><mi>A</mi></math></span> and <span><math><mi>B</mi></math></span> be two positive bounded linear operators acting on the complex Hilbert spaces <span><math><mi>H</mi></math></span> and <span><math><mi>K</mi></math></span>, respectively. In this paper, we study the <span><math><mrow><mo>(</mo><mi>A</mi><mo>⊗</mo><mi>B</mi><mo>)</mo></mrow></math></span>-numerical range <span><math><mrow><msub><mrow><mi>W</mi></mrow><mrow><mi>A</mi><mo>⊗</mo><mi>B</mi></mrow></msub><mrow><mo>(</mo><mi>T</mi><mo>⊗</mo><mi>S</mi><mo>)</mo></mrow></mrow></math></span> of the tensor product <span><math><mrow><mi>T</mi><mo>⊗</mo><mi>S</mi></mrow></math></span> for two bounded linear operators <span><math><mi>T</mi></math></span> and <span><math><mi>S</mi></math></span> on <span><math><mi>H</mi></math></span> and <span><math><mi>K</mi></math></span>, respectively. In the context of this work, we demonstrate that if either <span><math><mi>T</mi></math></span> is <span><math><mi>A</mi></math></span>-hyponormal or <span><math><mi>S</mi></math></span> is <span><math><mi>B</mi></math></span>-hyponormal, then <span><span><span><math><mrow><mover><mrow><msub><mrow><mi>W</mi></mrow><mrow><mi>A</mi><mo>⊗</mo><mi>B</mi></mrow></msub><mrow><mo>(</mo><mi>T</mi><mo>⊗</mo><mi>S</mi><mo>)</mo></mrow></mrow><mo>¯</mo></mover><mo>=</mo><mi>co</mi><mfenced><mrow><mover><mrow><msub><mrow><mi>W</mi></mrow><mrow><mi>A</mi></mrow></msub><mrow><mo>(</mo><mi>T</mi><mo>)</mo></mrow></mrow><mo>¯</mo></mover><mi>⋅</mi><mover><mrow><msub><mrow><mi>W</mi></mrow><mrow><mi>B</mi></mrow></msub><mrow><mo>(</mo><mi>S</mi><mo>)</mo></mrow></mrow><mo>¯</mo></mover></mrow></mfenced><mo>,</mo></mrow></math></span></span></span>where <span><math><mrow><msub><mrow><mi>W</mi></mrow><mrow><mi>A</mi></mrow></msub><mrow><mo>(</mo><mi>T</mi><mo>)</mo></mrow></mrow></math></span> and <span><math><mrow><msub><mrow><mi>W</mi></mrow><mrow><mi>B</mi></mrow></msub><mrow><mo>(</mo><mi>S</mi><mo>)</mo></mrow></mrow></math></span> denote the <span><math><mi>A</mi></math></span>-numerical range of <span><math><mi>T</mi></math></span> and the <span><math><mi>B</mi></math></span>-numerical range of <span><math><mi>S</mi></math></span>, respectively. Here, <span><math><mrow><mi>co</mi><mrow><mo>(</mo><mi>⋅</mi><mo>)</mo></mrow></mrow></math></span> and the over-line denote the convex hull and the closure, respectively. Moreover, we provide some <span><math><mrow><mo>(</mo><mi>A</mi><mo>⊗</mo><mi>B</mi><mo>)</mo></mrow></math></span>-numerical radius inequalities.</div></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"52 2","pages":"Article 100370"},"PeriodicalIF":1.2,"publicationDate":"2025-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143165747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Kuwait Journal of Science
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1