Anirudh Srivastava, Mukul Kumar, Doli Devi, Javed Masood Khan, Sandeep Kumar Singh
{"title":"Investigation of the effect of poly (sodium styrene sulfonate) on sodium glycodeoxycholate and sodium tetradecyl sulfate mixed micelle","authors":"Anirudh Srivastava, Mukul Kumar, Doli Devi, Javed Masood Khan, Sandeep Kumar Singh","doi":"10.1007/s00396-024-05263-w","DOIUrl":null,"url":null,"abstract":"<div><p>The interactions of polyelectrolyte poly (sodium styrene sulfonate or NaPSS) and anionic surfactants, sodium glycodeoxycholate (SGDC) and sodium tetradecyl sulfate (STS), as well as their combination (SGDC + STS) at different mole fraction ratios, were investigated using surface tension analysis. In the SGDC + STS binary mixture, when the amount of NaPSS (0.005–0.03%) increased from <span>\\({\\alpha }_{{\\text{SGDC}}}\\)</span> 0.0 to 1.0, increasing the critical micellization concentration (cmc) of the mixtures. The minimum cmc values were found from 0.833 to 1.480 mmol L<sup>−1</sup> in the presence of 0.03% of NaPSS. Clint, Rubingh, Motomura, and Rodenas approaches were used to evaluate the ideal cmc, activity coefficients (<i>f</i><sub>i</sub>), interaction parameter (–<i>β</i>), micellar compositions (<i>x</i>), and ideal micellar composition of (<i>x</i><sup><i>id</i></sup>) of SGDC + STS mixtures. Synergism has been demonstrated by the experimental values of <i>c</i><sub><i>0m</i></sub> being lower than the ideal values in water. Moreover, by adding NaPSS from 0.005 to 0.03%, the synergism interaction was eliminated and antagonism behavior was developed. The standard Gibb’s free energy of micellization (<span>\\({\\Delta G}_{m}^{0})\\)</span> and surface excess (<i>Γ</i>) and surface area per absorbed molecules (<i>A</i><sub>min</sub>) was decreased or increased depending on NaPSS amount in the SGDC + STS mixture with varying <span>\\({a}_{{\\text{SGDC}}}\\)</span>.</p></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid and Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s00396-024-05263-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The interactions of polyelectrolyte poly (sodium styrene sulfonate or NaPSS) and anionic surfactants, sodium glycodeoxycholate (SGDC) and sodium tetradecyl sulfate (STS), as well as their combination (SGDC + STS) at different mole fraction ratios, were investigated using surface tension analysis. In the SGDC + STS binary mixture, when the amount of NaPSS (0.005–0.03%) increased from \({\alpha }_{{\text{SGDC}}}\) 0.0 to 1.0, increasing the critical micellization concentration (cmc) of the mixtures. The minimum cmc values were found from 0.833 to 1.480 mmol L−1 in the presence of 0.03% of NaPSS. Clint, Rubingh, Motomura, and Rodenas approaches were used to evaluate the ideal cmc, activity coefficients (fi), interaction parameter (–β), micellar compositions (x), and ideal micellar composition of (xid) of SGDC + STS mixtures. Synergism has been demonstrated by the experimental values of c0m being lower than the ideal values in water. Moreover, by adding NaPSS from 0.005 to 0.03%, the synergism interaction was eliminated and antagonism behavior was developed. The standard Gibb’s free energy of micellization (\({\Delta G}_{m}^{0})\) and surface excess (Γ) and surface area per absorbed molecules (Amin) was decreased or increased depending on NaPSS amount in the SGDC + STS mixture with varying \({a}_{{\text{SGDC}}}\).
期刊介绍:
Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.