Real-time X-ray diffraction measurement on laser shock-loaded hexanitrostilbene (HNS)

IF 3.3 Q2 CHEMISTRY, MULTIDISCIPLINARY Energetic Materials Frontiers Pub Date : 2024-09-01 DOI:10.1016/j.enmf.2024.04.002
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Abstract

Understanding the lattice evolution of hexanitrostilbene (HNS) is crucial for ensuring its safety and reliability under shock loading. However, the lack of in situ, real-time diagnostics has limited the availability of lattice parameters for shock-loaded explosives. In this study, we utilized dynamic X-ray diffraction technology to obtain the diffraction spectrum of laser shock-loaded HNS and to determine its temporal evolution. Additionally, by improving the laser energy, we initiated HNS and obtained the diffraction spectrum of detonation products during the detonation process. The experimental results showed the presence of a diamond structure in the detonation product, suggesting the existence of either diamond or diamond-like carbon. Our research not only elucidates the crystal structure of shock-loaded HNS and its detonation products but also provides an avenue for laboratory-scale investigations into dynamically loaded explosives, which furnishing an opportunity to unveil the underlying mechanism governing explosive dynamic response behavior.

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激光冲击载荷己酮二苯乙烯(HNS)的实时 X 射线衍射测量
了解己酮二苯乙烯(HNS)的晶格演变对于确保其在冲击载荷下的安全性和可靠性至关重要。然而,由于缺乏原位实时诊断技术,限制了冲击加载炸药晶格参数的可用性。在本研究中,我们利用动态 X 射线衍射技术获得了激光冲击加载 HNS 的衍射谱,并确定了其时间演变。此外,通过提高激光能量,我们启动了 HNS 并获得了引爆过程中引爆产物的衍射谱。实验结果表明,引爆产物中存在金刚石结构,这表明存在金刚石或类金刚石碳。我们的研究不仅阐明了冲击载荷 HNS 及其引爆产物的晶体结构,还为实验室规模的动态载荷炸药研究提供了途径,为揭示炸药动态响应行为的内在机制提供了机会。
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来源期刊
Energetic Materials Frontiers
Energetic Materials Frontiers Materials Science-Materials Science (miscellaneous)
CiteScore
6.90
自引率
0.00%
发文量
42
审稿时长
12 weeks
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