Non-invasive measurement of spoilage of packed fish using halochromic sensor

Kesavan Devarayan, Yazhiniyan Palanisamy, Gangeswar Mohan, Anand Theivasigamani, Sabariswaran Kandasamy, Vimaladevi Sekar, Evon Umesh Siluvai John, M. Sukumaran, R. Marimuthu, Hema Anjappan
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Abstract

Purpose This study aims to develop a pH-functional thin-film sensor for non-invasive measurement of spoilage of packed fish. Design/methodology/approach At first, polymers of natural origin such as hydroxy(propyl)methyl cellulose, potato dextrose agar and starch alongside a pH sensitive-mixed indicator formulation were used to produce thin film sensor. The developed thin film sensor was tested for monitoring the spoilage of seafood stored at 4°C. Using ultraviolet-visible and Fourier-transform infrared spectroscopy, the halochromic sensor was characterised. In addition, the halochromic response of the thin film was directly correlated to the total volatile base nitrogen emitted by the packaged fish, pH, microbial activity and sensory evaluation. Findings The results suggested the developed biopolymer-based thin film sensor showed different colours in line with the spoilage of the packed fish, which could be well correlated with the total volatile base nitrogen, microbial activity and sensory evaluation. In addition, the thin film sensors exhibited a high degree of biodegradability. The biopolymers-based thin film halochromic sensor has exhibited excellent biodegradability along with sensitiveness towards the spoilage of the packed fish. Originality/value In the future, consumers and retailers may prefer seafood containers equipped with such halochromic sensors to determine the degree of food deterioration as a direct indicator of food quality.
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利用卤色传感器对包装鱼的腐败情况进行非侵入式测量
本研究旨在开发一种 pH 功能薄膜传感器,用于无创测量包装鱼类的变质情况。首先,使用羟(丙)甲基纤维素、马铃薯葡萄糖琼脂和淀粉等天然聚合物以及 pH 敏感的混合指示剂配方来制作薄膜传感器。对开发的薄膜传感器进行了测试,以监测储存在 4°C 的海产品的腐败情况。利用紫外-可见光光谱和傅立叶变换红外光谱对卤色传感器进行了表征。研究结果表明,所开发的基于生物聚合物的薄膜传感器会随着包装鱼的变质程度而呈现出不同的颜色,这与总挥发性基氮、微生物活性和感官评价有很好的相关性。此外,薄膜传感器还具有很高的生物降解性。原创性/价值今后,消费者和零售商可能会更喜欢装有这种卤色传感器的海鲜容器,以确定食品变质的程度,作为食品质量的直接指标。
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