Structural, morphological, optical and electrical properties of ferrite-based nanoparticles synthesized flexible substrate for chemical sensing application
Ismail Hossain , Mohammad Tariqul Islam , Norsuzlin Mohd Sahar , Md Samsuzzaman , Ahmed Alzamil , Mohamed S. Soliman
{"title":"Structural, morphological, optical and electrical properties of ferrite-based nanoparticles synthesized flexible substrate for chemical sensing application","authors":"Ismail Hossain , Mohammad Tariqul Islam , Norsuzlin Mohd Sahar , Md Samsuzzaman , Ahmed Alzamil , Mohamed S. Soliman","doi":"10.1016/j.jsamd.2024.100750","DOIUrl":null,"url":null,"abstract":"<div><p>A compact Ca<sub>x</sub>Co<sub>(0.90-x)</sub>Zn<sub>0.10</sub>Fe<sub>2</sub>O<sub>4</sub> based nanoparticles synthesized flexible microwave substrate with single negative (SNG) metamaterial is being successfully fabricated for industrial chemical contamination sensing applications. The unit cell dimensions of the MTM are 0.114λ × 0.114 λ × 0.017 λ. The nanoparticles, derived from the Ca<sub>x</sub>Co<sub>(0.90-x)</sub>Zn<sub>0.10</sub>Fe<sub>2</sub>O<sub>4</sub> material with varying Ca concentrations (Ca25, Ca50, and Ca75), have been synthesized using a sol-gel method, and their structural, morphological, and dielectric properties have been comprehensively characterized. Dielectric constants and loss tangents have been measured over the frequency range of 2–20 GHz. Simulation of the S<sub>21</sub> response at 3.43 GHz, 6.50 GHz, 11.49 GHz, and 16.46 GHz has yielded maximum magnitudes of −52.78 dB, −48.07 dB, −52.16 dB, and −39.37 dB, respectively. Experimental verification on an FR-4 rigid substrate at 3.28 GHz, 6.58 GHz, 11.76 GHz, and 16.33 GHz has revealed magnitudes of −25.67 dB, −24.56 dB, −31.13 dB, and −25.17 dB. Finally, when fabricated on the flexible microwave substrate, the MTM displayed S21 responses of −48.31 dB, −43.12 dB, −61.80 dB, and −24.70 dB at 3.19 GHz, 6.62 GHz, 11.58 GHz, and 16.65 GHz, respectively. The MTM has exhibited SNG properties in distinct frequency bands and near-zero index (NZI) characteristics. The sensitivity, figure of merit (FOM), and Q-factor have been achieved at 0.096 GHz/RIU, 0.152 GHz/RIU, 0.846 (RIU<sup>−1</sup>), 0.846 (RIU<sup>−1</sup>), and 8.430, 29.801, respectively. Its performance has been validated through simulation, VNA measurements, and advanced design system (ADS) software analysis, showcasing promise for diverse applications in S-, C-, X-, and Ku-bands. The anticipated structure performs well in terms of its small size, flexibility, sensitivity, and lightweight, making it suitable for wireless communications and methanol and ethanol contamination sensing in industrial applications.</p></div>","PeriodicalId":17219,"journal":{"name":"Journal of Science: Advanced Materials and Devices","volume":"9 3","pages":"Article 100750"},"PeriodicalIF":6.7000,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468217924000819/pdfft?md5=24172e638a0754e378ec04925e30687c&pid=1-s2.0-S2468217924000819-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Science: Advanced Materials and Devices","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468217924000819","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A compact CaxCo(0.90-x)Zn0.10Fe2O4 based nanoparticles synthesized flexible microwave substrate with single negative (SNG) metamaterial is being successfully fabricated for industrial chemical contamination sensing applications. The unit cell dimensions of the MTM are 0.114λ × 0.114 λ × 0.017 λ. The nanoparticles, derived from the CaxCo(0.90-x)Zn0.10Fe2O4 material with varying Ca concentrations (Ca25, Ca50, and Ca75), have been synthesized using a sol-gel method, and their structural, morphological, and dielectric properties have been comprehensively characterized. Dielectric constants and loss tangents have been measured over the frequency range of 2–20 GHz. Simulation of the S21 response at 3.43 GHz, 6.50 GHz, 11.49 GHz, and 16.46 GHz has yielded maximum magnitudes of −52.78 dB, −48.07 dB, −52.16 dB, and −39.37 dB, respectively. Experimental verification on an FR-4 rigid substrate at 3.28 GHz, 6.58 GHz, 11.76 GHz, and 16.33 GHz has revealed magnitudes of −25.67 dB, −24.56 dB, −31.13 dB, and −25.17 dB. Finally, when fabricated on the flexible microwave substrate, the MTM displayed S21 responses of −48.31 dB, −43.12 dB, −61.80 dB, and −24.70 dB at 3.19 GHz, 6.62 GHz, 11.58 GHz, and 16.65 GHz, respectively. The MTM has exhibited SNG properties in distinct frequency bands and near-zero index (NZI) characteristics. The sensitivity, figure of merit (FOM), and Q-factor have been achieved at 0.096 GHz/RIU, 0.152 GHz/RIU, 0.846 (RIU−1), 0.846 (RIU−1), and 8.430, 29.801, respectively. Its performance has been validated through simulation, VNA measurements, and advanced design system (ADS) software analysis, showcasing promise for diverse applications in S-, C-, X-, and Ku-bands. The anticipated structure performs well in terms of its small size, flexibility, sensitivity, and lightweight, making it suitable for wireless communications and methanol and ethanol contamination sensing in industrial applications.
期刊介绍:
In 1985, the Journal of Science was founded as a platform for publishing national and international research papers across various disciplines, including natural sciences, technology, social sciences, and humanities. Over the years, the journal has experienced remarkable growth in terms of quality, size, and scope. Today, it encompasses a diverse range of publications dedicated to academic research.
Considering the rapid expansion of materials science, we are pleased to introduce the Journal of Science: Advanced Materials and Devices. This new addition to our journal series offers researchers an exciting opportunity to publish their work on all aspects of materials science and technology within the esteemed Journal of Science.
With this development, we aim to revolutionize the way research in materials science is expressed and organized, further strengthening our commitment to promoting outstanding research across various scientific and technological fields.