{"title":"Construction of direct-Z-scheme heterojunction photocatalyst of g-C3N4/Ti3C2/TiO2 composite and its degradation behavior for dyes of Rhodamine B","authors":"","doi":"10.1016/j.cjche.2024.04.017","DOIUrl":null,"url":null,"abstract":"<div><p>Direct-Z-scheme g-C<sub>3</sub>N<sub>4</sub>/Ti<sub>3</sub>C<sub>2</sub>/TiO<sub>2</sub> photocatalyst with giant internal electric field was prepared by one-step aqueous sonication self-assembly method using g-C<sub>3</sub>N<sub>4</sub> and MXene of Ti<sub>3</sub>C<sub>2</sub> as the source materials. The chemical composition and structure of the catalysts was characterized by FT-IR, XRD, SEM, TEM, and XPS. The XPS characterization indicated that Ti<sub>3</sub>C<sub>2</sub> was partially oxidized to TiO<sub>2</sub> during the composite process. As a result, an efficient direct-Z-scheme heterojunction structure consisting of the g-C<sub>3</sub>N<sub>4</sub> and TiO<sub>2</sub> with Ti<sub>3</sub>C<sub>2</sub> as an electron bridge was constructed. The photocatalytic performance of the prepared catalysts was evaluated by degrading the rhodamine B (RhB) wastewater. Compared with the single g-C<sub>3</sub>N<sub>4</sub>, the g-C<sub>3</sub>N<sub>4</sub>/Ti<sub>3</sub>C<sub>2</sub>/TiO<sub>2</sub> composite photocatalyst exhibited efficient and stable photocatalytic degradation ability, with a degradation efficiency as high as 99.2% for RhB under optimal conditions (2% Ti<sub>3</sub>C<sub>2</sub>, pH = 3). The high degradation performance of g-C<sub>3</sub>N<sub>4</sub>/Ti<sub>3</sub>C<sub>2</sub>/TiO<sub>2</sub> for RhB was attributed to the combination of Ti<sub>3</sub>C<sub>2</sub>, TiO<sub>2</sub>, and g-C<sub>3</sub>N<sub>4</sub> components, forming a direct-Z-scheme heterojunction with a high-speed electron transport channel structure. The role of Z-scheme heterojunctions in electron transport is verified by photoelectrochemical characterization, along with photoluminescence (PL). Our research provides a simple method to design photocatalysts by constructing direct-Z-scheme electron transport channels for highly efficient treatment of dye wastewater.</p></div>","PeriodicalId":9966,"journal":{"name":"Chinese Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1004954124001678","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Direct-Z-scheme g-C3N4/Ti3C2/TiO2 photocatalyst with giant internal electric field was prepared by one-step aqueous sonication self-assembly method using g-C3N4 and MXene of Ti3C2 as the source materials. The chemical composition and structure of the catalysts was characterized by FT-IR, XRD, SEM, TEM, and XPS. The XPS characterization indicated that Ti3C2 was partially oxidized to TiO2 during the composite process. As a result, an efficient direct-Z-scheme heterojunction structure consisting of the g-C3N4 and TiO2 with Ti3C2 as an electron bridge was constructed. The photocatalytic performance of the prepared catalysts was evaluated by degrading the rhodamine B (RhB) wastewater. Compared with the single g-C3N4, the g-C3N4/Ti3C2/TiO2 composite photocatalyst exhibited efficient and stable photocatalytic degradation ability, with a degradation efficiency as high as 99.2% for RhB under optimal conditions (2% Ti3C2, pH = 3). The high degradation performance of g-C3N4/Ti3C2/TiO2 for RhB was attributed to the combination of Ti3C2, TiO2, and g-C3N4 components, forming a direct-Z-scheme heterojunction with a high-speed electron transport channel structure. The role of Z-scheme heterojunctions in electron transport is verified by photoelectrochemical characterization, along with photoluminescence (PL). Our research provides a simple method to design photocatalysts by constructing direct-Z-scheme electron transport channels for highly efficient treatment of dye wastewater.
期刊介绍:
The Chinese Journal of Chemical Engineering (Monthly, started in 1982) is the official journal of the Chemical Industry and Engineering Society of China and published by the Chemical Industry Press Co. Ltd. The aim of the journal is to develop the international exchange of scientific and technical information in the field of chemical engineering. It publishes original research papers that cover the major advancements and achievements in chemical engineering in China as well as some articles from overseas contributors.
The topics of journal include chemical engineering, chemical technology, biochemical engineering, energy and environmental engineering and other relevant fields. Papers are published on the basis of their relevance to theoretical research, practical application or potential uses in the industry as Research Papers, Communications, Reviews and Perspectives. Prominent domestic and overseas chemical experts and scholars have been invited to form an International Advisory Board and the Editorial Committee. It enjoys recognition among Chinese academia and industry as a reliable source of information of what is going on in chemical engineering research, both domestic and abroad.