Underoil superhydrophilic flame-retardant 3D porous composite for efficient on-demand emulsion separation: Interface engineering design on sphagnum moss

Abstract

Oil pollution and the energy crisis make oil-water separation an urgent for human need. The widespread use of materials with a single emulsion separation capability is limited. Multifunctional on-demand separation materials can adapt to a wide range of application scenarios, thus having a wider range of applications. The underoil superhydrophilic surface is of great significance for realizing the on-demand separation of oil/water emulsions through the removal of water in the oil and oil in the water. A 3D porous emulsion separation material based on the superhydrophilic principle of sphagnum moss was designed. The material was prepared in a simple step by taking advantage of the adhesion of polydopamine and the introduction of the as-prepared superhydrophilic BaSO₄ nanoparticles to achieve superhydrophilicity with a water contact angle (WCA) of 0° and an oil contact angle (OCA) of 157.3°, resulting in excellent separation performance for both water-in-oil and oil-in-water emulsions. Underoil superhydrophilic porous composite (OSPC) can complete two kinds of emulsion separations by filtration or adsorption. It adsorbs water from water-in-oil emulsion to achieve separation, with a good adsorption capacity of 74.38 g/g and efficiency up to 99%. It can also filter oil-in-water emulsions with an efficiency of 99.92%. The separation efficiencies are all almost unchanged after ten separation cycles. Furthermore, the material has excellent flame retardancy, which reduces the possibility of secondary disasters. The three-dimensional porous sponge has excellent on-demand separation performance for multiple emulsions. It provides a new preparation strategy for underoil superhydrophilic materials and a new idea for the design direction of special wetting materials for the on-demand separation of oil/water emulsions.