Cryochemical Synthesis of Tricalcium Phosphate Powders and Mixed Sodium-Containing Silicophosphates and Phosphate-Germanates for Formation of Bioceramics Using Stereolithographic 3D Printing

IF 0.5 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Inorganic Materials: Applied Research Pub Date : 2024-05-27 DOI:10.1134/s2075113324020308
D. S. Larionov, V. A. Bitanova, P. V. Evdokimov, A. V. Garshev, O. A. Shlyakhtin, V. I. Putlyaev
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Abstract

The issues of synthesis of highly dispersed chemically homogeneous powders based on glaserite-like phases in the CaO–Na2O–P2O5–SiO2 (GeO2) systems by a cryochemical method, including rapid freezing of a total salt solution, sublimation removal of ice, and subsequent thermolysis of a dehydrated salt precursor, are considered. The complex chemical composition of powders is necessary to create bioceramics from them with improved osteoplastic characteristics. Results of the synthesis of powders with submicron granulometry from solutions with different anionic composition are presented; the behavior of such powders during the sintering process is described.

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低温化学合成磷酸三钙粉末和含钠硅磷酸盐及磷酸盐-锗酸盐混合物,利用立体光刻三维打印技术形成生物陶瓷
摘要 本文探讨了在 CaO-Na2O-P2O5-SiO2 (GeO2) 体系中采用低温化学方法合成高度分散的化学均匀粉末的问题,该方法包括快速冷冻全盐溶液、升华除冰以及随后对脱水盐前体进行热解。粉末的复杂化学成分是用其制成具有更好骨塑性特征的生物陶瓷的必要条件。本文介绍了从具有不同阴离子成分的溶液中合成亚微米粒度粉末的结果;并描述了此类粉末在烧结过程中的行为。
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来源期刊
Inorganic Materials: Applied Research
Inorganic Materials: Applied Research Engineering-Engineering (all)
CiteScore
0.90
自引率
0.00%
发文量
199
期刊介绍: Inorganic Materials: Applied Research  contains translations of research articles devoted to applied aspects of inorganic materials. Best articles are selected from four Russian periodicals: Materialovedenie, Perspektivnye Materialy, Fizika i Khimiya Obrabotki Materialov, and Voprosy Materialovedeniya  and translated into English. The journal reports recent achievements in materials science: physical and chemical bases of materials science; effects of synergism in composite materials; computer simulations; creation of new materials (including carbon-based materials and ceramics, semiconductors, superconductors, composite materials, polymers, materials for nuclear engineering, materials for aircraft and space engineering, materials for quantum electronics, materials for electronics and optoelectronics, materials for nuclear and thermonuclear power engineering, radiation-hardened materials, materials for use in medicine, etc.); analytical techniques; structure–property relationships; nanostructures and nanotechnologies; advanced technologies; use of hydrogen in structural materials; and economic and environmental issues. The journal also considers engineering issues of materials processing with plasma, high-gradient crystallization, laser technology, and ultrasonic technology. Currently the journal does not accept direct submissions, but submissions to one of the source journals is possible.
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