METHODS OF INFLUENCE ON THE SYSTEM TO CHANGE THE ENERGY STATE OF SUBSTANCE: EXPERIENCE, STATE OF THE ISSUE

O.A. Huseinov, V.I. Zaporozhets
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Abstract

Methods of influencing the system, the ultimate goal of which is to destruct the natural structure of the material, can be divided as mechanical, physical, chemical, biological and complex. The changing the energy state of a substance is called activation. The current scientific field of ultradispersed materials and physical and chemical processes caused by dispersion is created by the researches of many scientists. Detailed consideration for the increasing reactivity of a solid substance compared to the change in its specific surface area during its mechanical activation showed that the share attributable to the growth of the specific surface area is only a few percent of the mechanical activation effect. The other part is due to the accumulation of defects in the crystals during the grinding process. According to the law of conservation of energy, when a crystal splits, the potential energy of interaction between lattice nodes is transferred to uncompensated surface energy. In addition, the value of the specific surface energy depends on the type of flat lattice used to split the crystal. Therefore, the activation processes and the application of the substance in the active state are relevant in the development of modern binders and concretes. The purpose of the article is to analyse the advantages and disadvantages of the existing methods of influencing the system with the ultimate goal of destruction of the natural structure of the material to changing the energy state of the substance, i.e. its activation. Conclusions. During the destruction of solids, the formation of new cleavage surfaces is accompanied by the breaking of bonds between the substance structural elements and the transition of the potential bond energy into surface energy. Ceteris paribus, the higher the ionic charges and the smaller the distance between them (between adjacent flat grids in the lattice), the greater the value of σ. In addition, the value of the specific surface energy depends on the type of flat grids used to split the crystal. It is worth mentioning that not all methods of activation for binder and concrete (soluble) mixtures are currently implemented on an i industry level. This is due to various reasons. The main method of activation used on an industry level is mechanochemical activation in various types of mills.
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影响系统以改变物质能量状态的方法:经验、问题的状态
影响系统的方法可分为机械、物理、化学、生物和复合方法,其最终目的是破坏物质的自然结构。改变物质的能量状态称为活化。目前,超分散材料以及由分散引起的物理和化学过程的科学领域是由许多科学家的研究创建的。在机械活化过程中,与比表面积的变化相比,对固体物质反应性增加的详细考虑表明,比表面积的增长只占机械活化效应的百分之几。另一部分是由于研磨过程中晶体中缺陷的积累。根据能量守恒定律,当晶体分裂时,晶格节点之间相互作用的势能会转移到未补偿的表面能上。此外,比表面能的值取决于用于分裂晶体的平面晶格类型。因此,活化过程和活性状态物质的应用与现代粘结剂和混凝土的开发息息相关。文章的目的是分析现有影响系统的方法的优缺点,最终目的是破坏材料的天然结构,改变物质的能量状态,即活化。结论。在破坏固体的过程中,伴随着物质结构元素之间键的断裂和潜在键能向表面能的转变,形成了新的裂隙表面。此外,比表面能的值取决于用于分裂晶体的平网格的类型。值得一提的是,目前并非所有的粘结剂和混凝土(可溶)混合物活化方法都能在工业层面上实施。这是由于各种原因造成的。工业上使用的主要活化方法是在各种碾磨机中进行机械化学活化。
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