Recent advancement in electrolyte optimization for rechargeable aqueous zinc–sulfur (Zn–S) batteries

IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Current Opinion in Electrochemistry Pub Date : 2024-06-14 DOI:10.1016/j.coelec.2024.101555
Liting Chen , Xiaoqing Liu , Yongchao Tang , Zhipeng Wen , Cheng Chao Li
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Abstract

Zinc–sulfur (Zn–S) batteries have attracted a lot of interest in the field of battery development due to their many benefits, which include their extremely high theoretical capacity and energy density, low cost, and excellent safety. However, the development of aqueous Zn–S batteries is hampered by the slow reaction kinetics of sulphur, lower discharge voltage, cathode volume expansion during zincation, and corrosion and hydrogen precipitation reactions of the negative electrode in aqueous electrolyte. These factors also seriously affect the cycle life of Zn–S batteries. This review outlines the advancements made in the field of aqueous electrolyte modification in Zn–S batteries in recent years, emphasises the significance of optimising aqueous electrolytes in raising Zn–S battery performance, and suggests future research avenues based on the findings of the current studies.

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可充电锌硫 (Zn-S) 水电池电解质优化的最新进展
锌-硫(Zn-S)电池因其理论容量和能量密度极高、成本低、安全性好等诸多优点,在电池开发领域引起了广泛关注。然而,由于硫的反应动力学缓慢、放电电压较低、锌化过程中阴极体积膨胀以及负极在水性电解液中的腐蚀和析氢反应等原因,水性锌-S 电池的开发受到了阻碍。这些因素也严重影响了锌-S 电池的循环寿命。本综述概述了近年来在锌-S 电池水电解质改性领域取得的进展,强调了优化水电解质对提高锌-S 电池性能的重要意义,并在现有研究成果的基础上提出了未来的研究方向。
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来源期刊
Current Opinion in Electrochemistry
Current Opinion in Electrochemistry Chemistry-Analytical Chemistry
CiteScore
14.00
自引率
5.90%
发文量
272
审稿时长
73 days
期刊介绍: The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner: 1.The views of experts on current advances in electrochemistry in a clear and readable form. 2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications. In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle: • Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •
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