Multilayer stacked ultra-wideband perfect solar absorber and thermal emitter based on SiO2-InAs-TiN nanofilm structure

IF 3.3 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-07-02 DOI:10.1039/D4DT01626B
Peng Chen, Qianju Song, Can Ma, Zao Yi, Liang Bian, Shubo Cheng, Zhiqiang Hao, Tangyou Sun, Pinghui Wu and Qingdong Zeng
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Abstract

In this paper, a broadband solar absorber is constructed and simulated based on the finite difference time domain method (FDTD). The modeled structure of the absorber consists of cyclic stacking of five absorber cells with different periods on refractory metal W, where a single absorber cell is composed of a three-layer SiO2-InAs-TiN square film. Due to the Fabry–Perot resonance and the surface plasmon resonance (SPR), an absorptivity greater than 90% within a bandwidth of 2599.5 nm was achieved for the absorber. Notably, one of these bands, 2001 nm, is a high-efficiency absorption with an absorption rate greater than 99%. The average absorption efficiency reaches 99.31% at an air mass of 1.5 (AM 1.5), and the thermal radiation efficiencies are 97.35% and 97.83% at 1000 K and 1200 K, respectively. At the same time, the structure of the absorber is also polarization-independent, and when the solar incidence angle is increased to 60°, it still achieves an average absorption of 90.83% over the entire wavelength band (280 nm to 3000 nm). The novelty of our work is to provide a design idea based on a unit structure with multiple cycles, which can effectively expand the absorption bandwidth of the absorber in the visible-near-infrared wavelengths. The excellent performances make the structure widely used in the field of solar energy absorption.

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基于 SiO2-InAs-TiN 纳米薄膜结构的多层叠加超宽带完美太阳能吸收器和热发射器
目前,太阳光的应用领域非常广泛,但太阳能吸收器对太阳光的吸收效率仍有待提高。本文设计了一种由五个循环堆叠吸收单元组成的太阳能吸收器结构,其中单个吸收单元是由三层 SiO2-InAs-TiN 薄膜组成的单元。通过在基底的难熔金属 W 上堆叠第一层吸收单元,随后的四个吸收单元有规律地减少循环,并按照我们的优化值 50 nm 依次堆叠,这样的设计增强了每个吸收单元边角的 SPR 以及吸收单元之间的法布里-珀罗共振耦合,最终实现了吸收器在 2599.5 nm 带宽内的完美吸收。值得注意的是,2001 nm 波段的吸收率超完美(A>99%)。经过有限差分时域法(FDTD)计算,其加权平均吸收率(AM1.5)为 99.31%。在 1000 K 和 1200 K 时,热辐射效率分别为 97.35% 和 97.83%。同时,吸收器的结构与偏振无关,太阳入射角也增加到了 60°,但它在整个波段(280 纳米到 3000 纳米)的平均吸收率仍然达到了 90.83%。值得注意的是,我们工作的创新之处在于设计了一种多层循环吸收器单元结构,它能有效地保持吸收器在可见光-近红外波段的吸收带宽,其较强的热辐射效率也可应用于热辐射器领域。
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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