Multilayer stacked ultra-wideband perfect solar absorber and thermal emitter based on SiO2-InAs-TiN nanofilm structure

IF 3.5 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-07-02 DOI:10.1039/d4dt01626b
Peng Chen, Qianju Song, Can Ma, Zao Yi, Liang Bian, Shubo Cheng, Zhiqiang hao, Tangyou Sun, Pinghui Wu, Qingdong Zeng
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Abstract

Currently, the application field of sunlight is huge, but the absorption efficiency of solar absorbers for sunlight still needs to be improved. In this paper, we design a solar absorber structure consisting of five cycles of stacked absorber units, where a single absorber unit is a cell consisting of a three-layer SiO2-InAs-TiN film. By stacking the first layer of absorber units on the refractory metal W of the substrate, the subsequent four absorber units reduce the cycles regularly and are stacked sequentially according to our optimized value of 50 nm, and such a design enhances the SPR at the corners of each absorber unit and the Fabry-Perot resonance coupling between absorber units, ultimately achieving the perfect absorption of the absorber in the bandwidth of 2599.5 nm. It is noteworthy that there is an ultra-perfect absorption (A>99%) in the band of 2001 nm. After the finite difference time domain method in time domain (FDTD) calculation, its weighted average absorption (AM1.5) is 99.31%. At 1000 K and 1200 K, the thermal radiation efficiency is 97.35% and 97.83%, respectively. Meanwhile, the structure of the absorber is independent of polarization, and the sun's incidence angle has increased to 60°, but it still achieves an average absorption of 90.83% over the whole wavelength band (280 to 3000 nm). It is worth noting that the innovation of our work lies in the design of a multilayer recycled absorber unit structure, which can efficiently maintain the absorber's absorption bandwidth in the visible-near-infrared wavelength band, and its strong thermal radiation efficiency can also be applied in the field of thermal emitters.
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基于 SiO2-InAs-TiN 纳米薄膜结构的多层叠加超宽带完美太阳能吸收器和热发射器
目前,太阳光的应用领域非常广泛,但太阳能吸收器对太阳光的吸收效率仍有待提高。本文设计了一种由五个循环堆叠吸收单元组成的太阳能吸收器结构,其中单个吸收单元是由三层 SiO2-InAs-TiN 薄膜组成的单元。通过在基底的难熔金属 W 上堆叠第一层吸收单元,随后的四个吸收单元有规律地减少循环,并按照我们的优化值 50 nm 依次堆叠,这样的设计增强了每个吸收单元边角的 SPR 以及吸收单元之间的法布里-珀罗共振耦合,最终实现了吸收器在 2599.5 nm 带宽内的完美吸收。值得注意的是,2001 nm 波段的吸收率超完美(A>99%)。经过有限差分时域法(FDTD)计算,其加权平均吸收率(AM1.5)为 99.31%。在 1000 K 和 1200 K 时,热辐射效率分别为 97.35% 和 97.83%。同时,吸收器的结构与偏振无关,太阳入射角也增加到了 60°,但它在整个波段(280 纳米到 3000 纳米)的平均吸收率仍然达到了 90.83%。值得注意的是,我们工作的创新之处在于设计了一种多层循环吸收器单元结构,它能有效地保持吸收器在可见光-近红外波段的吸收带宽,其较强的热辐射效率也可应用于热辐射器领域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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