Comparative study of pb(II) and cr(VI) removal using Cassava peel (Manihot Esculenta Crantz).

Abstract

The present study investigated the capability of cassava peel (Manihot Esculenta Crantz) in Pb(II) and Cr(VI) removal. The comparative study was conducted using batch method observing some parameters. The results indicated that the optimum adsorption of Pb(II) occurred at pH 5, initial concentration of 1000 mg/L, and contact time of 50 min. On the other hand, the optimal adsorption of Cr(VI) was achieved at pH 2, initial concentration of 1200 mg/L, and contact time of 70 min. The adsorption isotherms of both metals tended to follow the Langmuir model, while the adsorption kinetics suited to pseudo-second-order model. Thermodynamic parameters indicated that the adsorption process was spontaneous (ΔG° negative), endothermic (ΔH° positive), and exhibited surface dispersion on the biosorbent (ΔS° positive). Characterization using Fourier Transform Infrared (FTIR), X-Ray Fluorescence (XRF), Scanning Electron Microscopy (SEM), and Thermogravimetry (TGA) provided evidence of both physical and chemical adsorption. The adsorption capacity of cassava peel was also tested on samples collected approximately 30 m from the bay shoreline, resulting in a removal percentage of 94.67% for Pb(II) and 82.28% for Cr(VI) under optimal pH and contact time conditions.