A Review of Microwave Absorption and Reflection by Cement‐Based Materials, With Emphasis on Electromagnetic Interference Shielding and Admixture Effects

IF 18.5 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Advanced Functional Materials Pub Date : 2024-07-06 DOI:10.1002/adfm.202408220
D. D. L. Chung
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Abstract

Cement‐based materials can be modified for microwave reflection/absorption. Admixtures (particles or short fibers) include conductive, dielectric, and magnetic ones, used solely or in combination. Synergism occurs with conductive and magnetic admixtures, due to the enabled eddy current. The conductive admixture promotes absorption and reflection, whether steel rebars are present or not. Regardless of the admixtures, rebars, or aggregates, absorption loss dominates over reflection loss. Steel microfiber is more effective than carbon fiber. Fly ash enhances the absorption slightly, due to the included iron oxide. Because of the skin effect, a small admixture unit size is preferred. Thus, carbon nanofiber is more effective than carbon fiber, if it is adequately dispersed. Fine particles (such as silica fume) as an additional admixture help the dispersion. Nanoscale admixtures tend to fill the pores, so their functional effectiveness is limited. Carbon black (nanoparticles) is less effective than carbon fiber, but it is inexpensive and the combined use of carbon fiber and carbon black is effective. The high cost of the nanofibers and the difficulty of their dispersion limit their practicality. Another approach involves porous admixtures or aggregates for reducing the impedance mismatch so that reflection is lessened and more radiation enters the cement‐based material.
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水泥基材料对微波的吸收和反射综述,重点是电磁干扰屏蔽和混合效应
可以对水泥基材料进行改性,以实现微波反射/吸收。外加剂(颗粒或短纤维)包括导电、介电和磁性外加剂,可单独使用或混合使用。导电外加剂和磁性外加剂会因产生涡流而产生协同作用。无论是否存在钢筋,导电外加剂都会促进吸收和反射。无论使用哪种外加剂、钢筋或集料,吸收损耗都会超过反射损耗。超细钢纤维比碳纤维更有效。由于含有氧化铁,粉煤灰可略微增强吸收效果。由于表皮效应,掺合料的单位尺寸最好较小。因此,如果充分分散,纳米碳纤维比碳纤维更有效。细颗粒(如硅灰)作为额外的外加剂有助于分散。纳米级外加剂容易填充孔隙,因此其功能效果有限。碳黑(纳米颗粒)的效果不如碳纤维,但它价格低廉,同时使用碳纤维和碳黑也很有效。纳米纤维的高成本和分散难度限制了其实用性。另一种方法是使用多孔外加剂或集料来减少阻抗失配,从而减少反射,使更多辐射进入水泥基材料。
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来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
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