Dual modulation of electrolyte inner solvent structure and anode interface for high performance alkaline Al-air battery

IF 13.3 1区 工程技术 Q1 ENGINEERING, CHEMICAL Chemical Engineering Journal Pub Date : 2024-07-06 DOI:10.1016/j.cej.2024.153814
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Abstract

In this work, we propose a Water-in-salt electrolyte based on concentrated ionic additive for Al-air batteries, aiming at inhibiting the unexpected severe hydrogen evolution self-corrosion. Computing calculations and experimental characterizations consistently confirm that the additive can significantly affect both the solvent structure and anode interface. A stronger H-bonding network is reconfigured and formed in the electrolyte, thus leading to a dramatic decrease in free water content and activity. Besides, the adsorption behavior of used additive molecules on Al anode surface plays an activating and stabilizing role, which is conducive to promoting the uniform dissolution of Al anode and improving the electrochemical performance. Owing to this dual modulation, the electrolyte system endows Al-air battery with extremely low self-corrosion rate (reduced by 89.6%) and remarkable discharge capacity of 2623 mAh/g.

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用于高性能碱性铝-空气电池的电解质内溶剂结构和阳极界面双重调制技术
在这项工作中,我们提出了一种基于浓缩离子添加剂的盐包水电解质,用于铝-空气电池,旨在抑制意想不到的严重氢演化自腐蚀。计算和实验结果一致证实,添加剂能显著影响溶剂结构和阳极界面。在电解质中重新配置并形成了更强的氢键网络,从而导致自由水含量和活性的急剧下降。此外,所用添加剂分子在铝阳极表面的吸附行为起到了活化和稳定的作用,有利于促进铝阳极的均匀溶解,提高电化学性能。在这种双重调制作用下,电解液体系赋予了铝空气电池极低的自腐蚀率(降低了 89.6%)和 2623 mAh/g 的显著放电容量。
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来源期刊
Chemical Engineering Journal
Chemical Engineering Journal 工程技术-工程:化工
CiteScore
21.70
自引率
9.30%
发文量
6781
审稿时长
2.4 months
期刊介绍: The Chemical Engineering Journal is an international research journal that invites contributions of original and novel fundamental research. It aims to provide an international platform for presenting original fundamental research, interpretative reviews, and discussions on new developments in chemical engineering. The journal welcomes papers that describe novel theory and its practical application, as well as those that demonstrate the transfer of techniques from other disciplines. It also welcomes reports on carefully conducted experimental work that is soundly interpreted. The main focus of the journal is on original and rigorous research results that have broad significance. The Catalysis section within the Chemical Engineering Journal focuses specifically on Experimental and Theoretical studies in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. These studies have industrial impact on various sectors such as chemicals, energy, materials, foods, healthcare, and environmental protection.
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