Activated carbon from biomass waste candlenut shells (Aleurites moluccana) doped ZIF-67/Fe3O4 as advanced materials for supercapacitor

Muhammadin Hamid , Noor Haida Mohd Kaus , Syahrul Humaidi , Isnaeni Isnaeni , Amru Daulay , Indah Revita Saragi
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Abstract

Biomass waste candlenut shells, such as adsorbent carbon, can be utilized. Fe3O4 has great electrical conductivity, and ZIF-67 has diverse pores. Activated carbon, Fe3O4, and ZIF-67 were prepared to obtain a combination of these materials using the co-precipitation method. FTIR spectra show a peak at 1341 cm−1, which depicts the Fe-O bending vibration. At peak 1558 cm−1 shows C = N streching. The top of 1412 cm−1 and 991 cm−1 extend the full ring. The sp2 aromatic peak may be seen at 1150 cm-1C-H bond. The surface area is 17.76 m2/g, and the pore size is 14.99 nm. Coercivity is 119.63 Oe, which shows a strong magnet. The highlight of the study was activated carbon from biomass waste candlenut shells (Aleurites moluccana) doped ZIF-67 supported Fe3O4 with specific capacitance shows high. The diffusion percentage shows fewer electrolyte ions entering the active material, and resistance also showed low results. It can increase the percentage of capacitive ions, thus improving the electrode. Electrochemical results show 1335F/g of high specific capacity at 1 A/g current density. It indicates a suitable candidate material for supercapacitor electrodes.

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掺杂 ZIF-67/Fe3O4 的生物质废烛台壳(Aleurites moluccana)活性炭作为超级电容器的先进材料
生物质废烛台壳可用作吸附碳。Fe3O4 具有很强的导电性,ZIF-67 具有多种孔隙。利用共沉淀法制备了活性炭、Fe3O4 和 ZIF-67,得到了这些材料的组合。傅立叶变换红外光谱显示,在 1341 cm-1 处有一个峰,描述了 Fe-O 的弯曲振动。1558 cm-1 处的峰值显示了 C = N 的条纹。1412 cm-1 和 991 cm-1 顶部延伸了整个环。在 1150 cm-1C-H 键处可以看到 sp2 芳香族峰。表面积为 17.76 m2/g,孔径为 14.99 nm。矫顽力为 119.63 Oe,显示出较强的磁性。该研究的亮点是生物质废弃物蜡烛果壳(Aleurites moluccana)掺杂 ZIF-67 的活性炭,其支持的 Fe3O4 具有较高的比电容。扩散百分比表明,进入活性材料的电解质离子较少,电阻也较低。它可以增加电容离子的百分比,从而改善电极。电化学结果显示,在电流密度为 1 A/g 时,比容量高达 1335F/g。这表明它是超级电容器电极的合适候选材料。
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来源期刊
Materials Science for Energy Technologies
Materials Science for Energy Technologies Materials Science-Materials Science (miscellaneous)
CiteScore
16.50
自引率
0.00%
发文量
41
审稿时长
39 days
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