The transformation of ferromagnetic properties of Fe3O4 into ferromagnetic properties of α-Fe2O3 by the polyol process, heat treatment, isothermally annealing and sintering

Nguyen Viet Long, Thi Nhat Hang Nguyen, Hong Phuc Le, Van Cuu Ho, Huu Tri Nguyen
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Abstract

In our present research, we have presented research on synthesizing micro/nanosized Fe3O4 (magnetite-type) by the polyol process, heat treatment, annealing and sintering processes. The structural change of the above material from low temperature to high temperature, the magnetic change of ferromagnetism of Fe3O4 into ferromagnetism of α-Fe2O3  when the as-prepared samples of Fe3O4 and α-Fe2O3 oxides are isothermally treated from low temperature to high temperature. Finally, it is experimentally confirmed that a significant structural change of magnetite-type micro/nanosized Fe3O4 oxides into the structure of hematite-type micro/nanosized α-Fe2O3 oxides (hematite-type).
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通过多元醇工艺、热处理、等温退火和烧结将 Fe3O4 的铁磁性转变为 α-Fe2O3 的铁磁性
在本研究中,我们介绍了通过多元醇工艺、热处理、退火和烧结过程合成微/纳米化 Fe3O4(磁铁矿型)的研究。从低温到高温等温处理制备的 Fe3O4 和 α-Fe2O3 氧化物样品时,上述材料从低温到高温的结构变化,Fe3O4 的铁磁性转变为 α-Fe2O3 的铁磁性。最后,实验证实磁铁矿型微/纳米化 Fe3O4 氧化物的结构发生了显著变化,变成了赤铁矿型微/纳米化 α-Fe2O3 氧化物(赤铁矿型)结构。
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