Operation enhancement of the H2 shaft furnace: a numerical study on the impact of N2 mixing in feed gas

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-07-15 DOI:10.1515/ijcre-2024-0043
Shan Yu, Lei Shao, Zongshu Zou
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Abstract

Focusing on improving the performance of the hydrogen (H2)-based direct reduction shaft furnace (HSF), the current work was undertaken to evaluate the potential benefits of an operation featuring nitrogen (N2) mixing in feed gas using a computational fluid dynamics (CFD) model that describes the in-furnace gas-solid countercurrent reactive flows. A set of simulation cases was carried out under different N2 flow rates and top pressures. Variation in the latter operating parameter was conducted with the intent to mitigate the issue of H2 dilution caused by N2 mixing. The results showed that the in-furnace thermochemical state deteriorates if the N2 flow rate is inadequate. The state is gradually improved by increasing the N2 flow rate as more sensible heat is delivered into the process, thereby resulting in better degrees of solid reduction and H2 utilization. An increase in the top pressure gives rise to higher gas density that enhances the driving force and thus facilitates the reduction reaction. A higher solid reduction degree is consequently achieved by elevating the top pressure. When the top pressure exceeds 5.0 atm, however, the increase in solid reduction degree becomes marginal, while the energy required for compressing the feed gas continues to rise linearly.
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H2 竖炉的运行改进:关于原料气中 N2 混合影响的数值研究
为了提高以氢(H2)为基础的直接还原竖炉(HSF)的性能,目前的工作是利用描述炉内气体-固体逆流反应流的计算流体动力学(CFD)模型,评估以氮气(N2)混入原料气为特征的操作的潜在益处。在不同的 N2 流速和顶压条件下进行了一系列模拟。对后一个操作参数进行了改变,目的是减轻 N2 混合造成的 H2 稀释问题。结果表明,如果 N2 流速不足,炉内热化学状态就会恶化。随着更多的显热被输送到工艺中,N2 流量的增加会逐渐改善热化学状态,从而提高固体还原度和 H2 利用率。顶部压力的增加会提高气体密度,从而增强驱动力,促进还原反应。因此,通过提高顶压可以实现更高的固体还原度。然而,当顶压超过 5.0 atm 时,固体还原度的提高变得微不足道,而压缩原料气体所需的能量则继续呈线性上升。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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