Investigation on NO and N2O emissions characteristics in deep peak regulation circulating fluidized bed boilers

IF 1.2 4区 工程技术 Q4 ENGINEERING, CHEMICAL International Journal of Chemical Reactor Engineering Pub Date : 2024-07-12 DOI:10.1515/ijcre-2024-0103
Fengxia An, Yiwen Zhang, Lingyan Le, Ying Yu, Fanhui Shen, Kang Yang, Haitao Hu, Fan Ye, Hui Wang
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Abstract

To adapt to the increasing proportion of new energy power generation capacity, coal power must transition from its traditional role as the primary power source to serving as a fundamental backup and system regulation energy source. The circulating fluidized bed technology is known for its wide range of load regulation capabilities; however, emissions of pollutants during load regulation can exhibit significant variability. This study utilized Aspen Plus software to develop a circulating fluidized bed combustion model based on a gas-solid fluid dynamics model, an equivalent coal pyrolysis model, and a multi-phase macroscopic combustion reaction dynamics model of pyrolysis products. This model was used to predict both the temperature distribution within the furnace chamber and the distribution of pollutant concentrations. Predictions of pollutant emissions from 100 % load to 30 % load of the circulating fluidized bed were explored under the original combustion condition and 5 % proportion of recirculated flue gas. Under the primary combustion condition, the emission concentration of NO x showed a decreasing and then increasing trend with decreasing load, while the concentration of nitrous oxide, in contrast to NO x , showed an increasing and then decreasing trend. The effect of recirculated flue gas on pollutant emissions was not significant at reduced loads. This study aims to provide technical support and theoretical guidance for the management of pollutant emissions from the deep peak regulation of actual circulating fluidized beds.
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深度调峰循环流化床锅炉 NO 和 N2O 排放特性研究
为适应新能源发电能力比例不断增加的趋势,煤电必须从传统的主要电源角色过渡到基本的备用和系统调节能源。循环流化床技术以其广泛的负荷调节能力而闻名,但在负荷调节过程中,污染物的排放会表现出显著的可变性。本研究利用 Aspen Plus 软件开发了循环流化床燃烧模型,该模型基于气固流体动力学模型、等效煤热解模型和热解产物的多相宏观燃烧反应动力学模型。该模型用于预测炉膛内的温度分布和污染物浓度分布。在原始燃烧条件和 5% 的再循环烟气比例下,对循环流化床从 100% 负荷到 30% 负荷的污染物排放进行了预测。在原燃烧条件下,氮氧化物的排放浓度随着负荷的降低呈先降低后升高的趋势,而氧化亚氮的浓度则与氮氧化物相反,呈先升高后降低的趋势。在降低负荷时,再循环烟气对污染物排放的影响并不显著。本研究旨在为实际循环流化床深度调峰污染物排放管理提供技术支持和理论指导。
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来源期刊
CiteScore
2.70
自引率
12.50%
发文量
107
审稿时长
6-12 weeks
期刊介绍: The International Journal of Chemical Reactor Engineering covers the broad fields of theoretical and applied reactor engineering. The IJCRE covers topics drawn from the substantial areas of overlap between catalysis, reaction and reactor engineering. The journal is presently edited by Hugo de Lasa and Charles Xu, counting with an impressive list of Editorial Board leading specialists in chemical reactor engineering. Authors include notable international professors and R&D industry leaders.
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