ZnO:CuO Composites Obtained by Rapid Joule Heating for Photocatalysis

Materials Pub Date : 2024-07-15 DOI:10.3390/ma17143502
Adrián Fernández-Calzado, Aarón Calvo-Villoslada, Paloma Fernández, Belén Sotillo
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Abstract

Semiconductor oxides belonging to various families are ideal candidates for application in photocatalytic processes. One of the challenges facing photocatalytic processes today is improving their efficiency under sunlight irradiation. In this study, the growth and characterization of semiconductor oxide nanostructures and composites based on the ZnO and CuO families are proposed. The selected growth method is the resistive heating of Zn and Cu wires to produce the corresponding oxides, combined with galvanic corrosion of Zn. An exhaustive characterization of the materials obtained has been carried out using techniques based on scanning electron microscopy and optical spectroscopies. The method we have followed and the conditions used in this study present promising results, not only from a degradation efficiency point of view but also because it is a cheap, easy, and fast growth method. These characteristics are essential in order to scale the process beyond the laboratory.
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通过快速焦耳加热获得的用于光催化的氧化锌:氧化铜复合材料
不同系列的半导体氧化物是光催化工艺的理想候选材料。当今光催化过程面临的挑战之一是提高其在阳光照射下的效率。本研究提出了基于氧化锌和氧化铜家族的半导体氧化物纳米结构和复合材料的生长和表征方法。所选的生长方法是通过电阻加热 Zn 和 Cu 线来产生相应的氧化物,同时结合 Zn 的电化学腐蚀。我们利用扫描电子显微镜和光学光谱技术对获得的材料进行了详尽的表征。我们在这项研究中所采用的方法和条件,不仅从降解效率的角度来看,而且还因为它是一种廉价、简便和快速的生长方法,而呈现出良好的结果。这些特点对于将这一过程推广到实验室以外的领域至关重要。
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