Preparation and Properties of Lightweight Aggregates from Discarded Al2O3-ZrO2-C Refractories

Materials Pub Date : 2024-08-09 DOI:10.3390/ma17163968
Shuli Sun, Junfeng Qu, Mengyong Sun, Xinming Ren, Cheng Gong, Xin Mu, W. Zan, Zhangyan Zhou, Chengji Deng, B. Ma
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Abstract

Refractory materials are an important pillar for the stable development of the high-temperature industry. A large amount of waste refractories needs to be further disposed of every year, so it is of great significance to carry out research on the recycling of used refractories. In this work, lightweight composite aggregate was prepared by using discarded Al2O3-ZrO2-C refractories as the main raw material, and the performance of the prepared lightweight aggregate was improved by adjusting the calcination temperature and introducing light calcined magnesia additives. The results showed that the cold compressive strength and thermal shock resistance of the lightweight aggregates were significantly improved with increasing calcination temperature. Moreover, the introduction of light calcined magnesia can effectively improve the apparent porosity, cold compressive strength, and thermal shock resistance of the prepared lightweight aggregates at the calcination temperature of 1400 °C. Consequently, this work provides a useful reference for the resource utilization of used refractories, while the prepared lightweight aggregates are expected to be applied in the field of high-temperature insulation.
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利用废弃的 Al2O3-ZrO2-C 耐火材料制备轻质骨料及其特性
耐火材料是高温工业稳定发展的重要支柱。每年都有大量废弃耐火材料需要进一步处理,因此开展废旧耐火材料的回收利用研究具有重要意义。本研究以废弃的 Al2O3-ZrO2-C 耐火材料为主要原料制备了轻质复合骨料,并通过调整煅烧温度和引入轻质煅烧镁质添加剂改善了所制备轻质骨料的性能。结果表明,随着煅烧温度的升高,轻质骨料的冷抗压强度和抗热震性能显著提高。此外,在煅烧温度为 1400 ℃ 时,引入轻质煅烧镁能有效改善制备的轻质骨料的表观孔隙率、冷抗压强度和抗热震性。因此,这项工作为废旧耐火材料的资源化利用提供了有益的参考,而制备的轻质骨料有望应用于高温隔热领域。
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