Late La Tène bronze rivets from selected sites in Bohemia: material research

IF 2.6 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Heritage Science Pub Date : 2024-07-24 DOI:10.1186/s40494-024-01338-7
Sarka Msallamova, Zuzana Zlamalova Cilova, Viktoria Cistakova, Zdenek Benes, Jan Dudak, Jan Zemlicka, Veronika Tymlova, Jan Krejci, Jitka Mikova, Josef Soucek
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Abstract

The study presented focuses on material research of La Tène rivets and represents the very first study conducted into this class of archaeological finds from the Bohemian region. The rivets examined come from two significant archaeological sites situated in this geographical area—a hillfort Kolo near Týnec nad Labem and an oppidum in Stradonice. The sets of the rivets selected for the study were dated to the Late La Tène period (second–first century BC)—in the context of Western Europe, the term Celtic period can also be found. Thorough material research of the objects utilised a range of methods such as scanning electron microscopy with energy dispersive analyser, atomic absorption spectrometry, X-ray micro-tomography scanning, laser ablation-inductively coupled plasma-mass spectrometry, and Raman spectrometry. As a result, the research has identified and described three different technologies used to produce the rivets. The rivets uncovered there were mostly produced by casting from a bronze alloy or by putting wrought iron pins into the bronze melt of rivet heads. In addition, a minority of the rivets were produced using forged wrought iron with their heads plated with a very thin bronze plate. The results of the elemental analysis showed that several of the rivets and most of the rivet heads were made of bronze alloys with a tin content of 2–10 wt.%. The lead content of bronze alloy rivets from both sites varies from 0.2 to 10.1 wt.%. It can be assumed, that lead was intentionally added to the bronze melt used to produce the majority of the artefacts examined. Also, several bronze rivet heads were found to be decorated with enamel, which is a type of soda-lime-silica high lead glass coloured with crystals of Cu2O (the Colour of the enamel was predominantly red). In conclusion, two different groups of enamels were distinguished: (a) enamels with PbO up to 20% and (b) enamels with a higher content of PbO reaching up to 40%.

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波希米亚部分遗址出土的拉泰纳晚期青铜铆钉:材料研究
本研究报告的重点是对拉泰纳铆钉的材料研究,是对波希米亚地区这类考古发现的首次研究。所研究的铆钉来自该地区的两个重要考古遗址--拉贝河畔蒂内茨附近的科洛山堡和斯特拉多尼采的一个oppidum。为本研究选取的铆钉的年代为拉泰纳晚期(公元前 2-1 世纪)--在西欧,也可以找到凯尔特时期这一术语。利用一系列方法对这些物品进行了彻底的材料研究,如扫描电子显微镜与能量色散分析仪、原子吸收光谱分析法、X 射线显微层析成像扫描法、激光烧蚀-电感耦合等离子体质谱分析法和拉曼光谱分析法。研究结果确定并描述了用于生产铆钉的三种不同技术。在那里发现的铆钉大多是用青铜合金铸造而成,或将锻铁销钉放入铆钉头的青铜熔体中。此外,还有少数铆钉是用锻铁制作的,其头部镀有一层很薄的青铜板。元素分析结果表明,一些铆钉和大部分铆钉头是由含锡量为 2-10 重量%的青铜合金制成的。两个地点的青铜合金铆钉的铅含量从 0.2 重量%到 10.1 重量%不等。可以推测,铅是有意添加到青铜熔液中的,用于生产大部分受检文物。此外,还发现一些青铜铆钉头饰有珐琅,珐琅是一种用 Cu2O 晶体着色的钠钙硅高铅玻璃(珐琅的颜色以红色为主)。总之,珐琅分为两类:(a) 氧化铅含量不超过 20% 的珐琅和 (b) 氧化铅含量高达 40% 的珐琅。
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来源期刊
Heritage Science
Heritage Science Arts and Humanities-Conservation
CiteScore
4.00
自引率
20.00%
发文量
183
审稿时长
19 weeks
期刊介绍: Heritage Science is an open access journal publishing original peer-reviewed research covering: Understanding of the manufacturing processes, provenances, and environmental contexts of material types, objects, and buildings, of cultural significance including their historical significance. Understanding and prediction of physico-chemical and biological degradation processes of cultural artefacts, including climate change, and predictive heritage studies. Development and application of analytical and imaging methods or equipments for non-invasive, non-destructive or portable analysis of artwork and objects of cultural significance to identify component materials, degradation products and deterioration markers. Development and application of invasive and destructive methods for understanding the provenance of objects of cultural significance. Development and critical assessment of treatment materials and methods for artwork and objects of cultural significance. Development and application of statistical methods and algorithms for data analysis to further understanding of culturally significant objects. Publication of reference and corpus datasets as supplementary information to the statistical and analytical studies above. Description of novel technologies that can assist in the understanding of cultural heritage.
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