The Museum of Sun Yat-sen University houses a collection of antique glass slides dating back to the 1940s. These historical artifacts not only serve as a record of the past but also bring history to life. During extended storage, the emulsion layer on glass slides may harden and become brittle, leading to cracking and buckling. This study suggests a method to enhance the physical property of the emulsion layer by using a combination of nonionic surfactant isomeric alcohol ethoxylates eight (TO-8) and waterborne epoxy resin (WER). We investigated the microscopic action mechanism of the two on the emulsion layer of glass slides using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), water contact angles, and other techniques. Our study revealed that TO-8 can significantly eliminate the spherulitic crystal structure of the emulsion layer, as well as improve its softness and hydrophilicity. The addition of the WER ensures that the cracking and warping of the emulsion layer film is fully corrected, resulting in a flat surface. Additionally, the size of the emulsion layer film remains stable even after wetting. The WER has minimal impact on the image information of glass slides. The emulsion layer of the glass slides, restored using the softening protection solutions developed in this study, showed almost full recovery of image information. This research holds significant theoretical and practical value for repairing cracked and warped emulsion layers on glass slides.
{"title":"Study on the restoration of glass slides dating back to the 1940s","authors":"Yuyao Ruan, Yanli Li, Fei Yang, Yanru Chen, Panpan Liu, Mantang Ge, Kezhu Han, Yuhu Li","doi":"10.1186/s40494-024-01454-4","DOIUrl":"https://doi.org/10.1186/s40494-024-01454-4","url":null,"abstract":"<p>The Museum of Sun Yat-sen University houses a collection of antique glass slides dating back to the 1940s. These historical artifacts not only serve as a record of the past but also bring history to life. During extended storage, the emulsion layer on glass slides may harden and become brittle, leading to cracking and buckling. This study suggests a method to enhance the physical property of the emulsion layer by using a combination of nonionic surfactant isomeric alcohol ethoxylates eight (TO-8) and waterborne epoxy resin (WER). We investigated the microscopic action mechanism of the two on the emulsion layer of glass slides using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), water contact angles, and other techniques. Our study revealed that TO-8 can significantly eliminate the spherulitic crystal structure of the emulsion layer, as well as improve its softness and hydrophilicity. The addition of the WER ensures that the cracking and warping of the emulsion layer film is fully corrected, resulting in a flat surface. Additionally, the size of the emulsion layer film remains stable even after wetting. The WER has minimal impact on the image information of glass slides. The emulsion layer of the glass slides, restored using the softening protection solutions developed in this study, showed almost full recovery of image information. This research holds significant theoretical and practical value for repairing cracked and warped emulsion layers on glass slides.</p>","PeriodicalId":13109,"journal":{"name":"Heritage Science","volume":"11 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"艺术学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-18DOI: 10.1186/s40494-024-01442-8
Benedetta Paolino, Maria Cristina Sorrentino, Severina Pacifico
Eco-friendly decontamination treatments on works of art made from organic materials are of growing interest. The high risks to human health and the environment associated with traditional biocides (e.g. ecotoxicity, development of biotic resistance) have made it necessary to search for safer alternatives, also looking at the past but innovating it. The current state of the art is explored here, delving into the literature on the topic from 2000 to today, and outlining trends in terms of the most tested artistic supports and types of published research (in vitro/in vivo). An overview of the characteristics and mechanisms of biodegradation processes on different types of organic products and on the microorganisms mainly involved is thus provided. The main chemical-physical action techniques tested are illustrated and their practical-applicative aspects are discussed on the basis of evidence from case studies. Taking stock of the actual situation, literature consultation highlights that if on the one hand research is advancing rapidly towards the discovery of new ecological and safe solutions, on the other hand these are often biocidal treatments whose protocols have yet to be explored and validated.
{"title":"Greener solutions for biodeterioration of organic-media cultural heritage: where are we?","authors":"Benedetta Paolino, Maria Cristina Sorrentino, Severina Pacifico","doi":"10.1186/s40494-024-01442-8","DOIUrl":"https://doi.org/10.1186/s40494-024-01442-8","url":null,"abstract":"<p>Eco-friendly decontamination treatments on works of art made from organic materials are of growing interest. The high risks to human health and the environment associated with traditional biocides (<i>e.g.</i> ecotoxicity, development of biotic resistance) have made it necessary to search for safer alternatives, also looking at the past but innovating it. The current state of the art is explored here, delving into the literature on the topic from 2000 to today, and outlining trends in terms of the most tested artistic supports and types of published research (in vitro/in vivo). An overview of the characteristics and mechanisms of biodegradation processes on different types of organic products and on the microorganisms mainly involved is thus provided. The main chemical-physical action techniques tested are illustrated and their practical-applicative aspects are discussed on the basis of evidence from case studies. Taking stock of the actual situation, literature consultation highlights that if on the one hand research is advancing rapidly towards the discovery of new ecological and safe solutions, on the other hand these are often biocidal treatments whose protocols have yet to be explored and validated.</p>","PeriodicalId":13109,"journal":{"name":"Heritage Science","volume":"74 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"艺术学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-17DOI: 10.1186/s40494-024-01452-6
Anna Ermolyuk, Darya Avdanina, Adelya Khayrova, Sergey Lopatin, Kirill Shumikhin, Tat’yana Kolganova, Nikolay Simonenko, Alexey Lunkov, Valery Varlamov, Mikhail Shitov, Alexander Zhgun
Microorganisms are a significant cause of damage to cultural heritage, including paintings. Currently, the palette of antiseptics that are used in painting has narrowed considerably. This is due to the increased demands placed on such substances. It was shown that low molecular weight chitosan (LMWC) obtained from the king crab (Paralithodes camtschaticus) exhibits high activity against dominant fungi-destructors of paintings in the State Tretyakov Gallery. Nevertheless, the increasing market demand for chitosan has prompted the exploration of alternative sources. Insects, notably the bioconverter black soldier fly (Hermetia illucens), stand out as one of the most cultivated options. This study investigates the effectiveness of chitosan, isolated from H. illucens by a novel method developed by authors, in inhibiting fungi that damage tempera paintings. The activity of 33 and 39 kDa chitosans from H. illucens is comparable to the most active chitosans previously studied from P. camtschaticus. However, there are characteristic differences between these compounds, as shown by the results of FTIR spectroscopy, which may affect their consumer properties when used in paint materials. Our studies suggest that LMWC from H. illucens is a promising material that can expand the range of antiseptics used in painting.