Effective electrode preparation and evaluation of crevice-free steel electrodes

M. A. Frontini, Marcela Vázquez, M. Valcarce
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Abstract

Crevice corrosion is hard to avoid when the corrosion resistance of steel electrodes needs to be evaluated in laboratory tests. It is particularly difficult when chloride ions are present in the electrolyte. This problem is recurrent when studying the performance of construction steel in concrete pore-simulating solutions that replicate marine exposure. Other steel applications in aggressive environments face the same problem. This study describes a simple pre-treatment implemented on the steel bars before the electrodes were constructed, which successfully minimizes the risk of electrodes showing crevice after an electrochemical evaluation in chloride-rich electrolytes. The pre-treatment efficacy can last from several months to years, depending on how frequently the electrodes are used.
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有效制备电极和评估无裂缝钢电极
在实验室测试中需要评估钢电极的耐腐蚀性时,很难避免缝隙腐蚀。当电解液中含有氯离子时,这一问题尤其难以解决。在研究建筑钢材在混凝土孔隙模拟溶液中的性能时,这个问题经常出现。在腐蚀性环境中应用的其他钢材也面临同样的问题。本研究介绍了在制作电极前对钢筋进行简单预处理的方法,该方法成功地将电极在富含氯化物的电解液中进行电化学评估后出现缝隙的风险降至最低。根据电极的使用频率,预处理效果可持续数月至数年不等。
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