Injection 3D Printing of Doubly Curved Ceramic Shells in Non-Synthetic Particle Suspensions

Materials Pub Date : 2024-08-09 DOI:10.3390/ma17163955
Vesela Tabakova, Christina Klug, Thomas H. Schmitz
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Abstract

This paper examines the application of non-synthetic particle suspensions as a support medium for the additive manufacturing of complex doubly curved ceramic shells with overhangs between 0° and 90° using clay paste. In this method, the build-up material is injected within a constant volume of air-permeable particle suspension. As the used clay paste does not solidify right after injection, the suspension operates like a support medium and enables various print path strategies. Different non-synthetic suspension mixtures, including solid and flexible components such as quartz sand, refractory clay, various types of wood shavings, and cotton flocks, were evaluated for their ability to securely hold the injected material while allowing drying of the water-based clay body and its shrinkage. The balance between grain composition, added water, and the compressibility of the mixture during printing and drying played a pivotal role in the particle suspension design and assessment. Furthermore, the moisture absorption of the particle suspension and the structural integrity of the layer bond of the fired ceramics were also assessed. The examined additive manufacturing process not only enables the production of meso-scale doubly curved ceramic shells with average overhang of 56° but also introduces a new practice for designing specialized surfaces and constructions.
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非合成粒子悬浮液中双曲面陶瓷壳的注塑 3D 打印
本文研究了将非合成颗粒悬浮液作为支撑介质,使用粘土浆增材制造悬伸角度在 0° 至 90° 之间的复杂双曲面陶瓷壳体的应用。在这种方法中,堆积材料被注入恒定体积的透气颗粒悬浮液中。由于所使用的粘土浆在注入后不会立即凝固,因此悬浮液就像一种支撑介质,可以实现各种打印路径策略。对不同的非合成悬浮混合物(包括固体和柔性成分,如石英砂、耐火粘土、各种类型的木屑和棉絮)进行了评估,以确定它们是否能够牢牢固定注入的材料,同时允许水基粘土体干燥和收缩。在颗粒悬浮液的设计和评估过程中,颗粒成分、添加水量以及印刷和干燥过程中混合物的可压缩性之间的平衡起着关键作用。此外,还评估了颗粒悬浮液的吸湿性和烧制陶瓷层结合的结构完整性。所研究的增材制造工艺不仅能够生产出平均悬伸角度为 56° 的中尺度双曲面陶瓷壳体,还为设计专用表面和结构引入了一种新的实践方法。
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