{"title":"Instant Upcycling of Microplastics into Graphene and Its Environmental Application","authors":"Muhammad Adeel Zafar, Mohan V. Jacob","doi":"10.1002/smsc.202400176","DOIUrl":null,"url":null,"abstract":"Microplastic pollution poses a growing threat to ecosystems globally, necessitating sustainable solutions. This study explores upcycling microplastics into graphene as a promising approach Traditional methods like pyrolysis and catalytic carbonization are slow and compromise graphene quality. Flash Joule heating is fast but energy-intensive and hard to control. In contrast, atmospheric pressure microwave plasma (APMP) synthesis, the proposed technique, offers a one-step, environmentally friendly alternative. APMP operates at relatively lower temperatures, reducing energy consumption and providing precise control over process parameters. This study demonstrates that polyethylene microplastics from waste dropper bottles can be efficiently transformed into graphene using APMP synthesis. Raman spectroscopy of synthesized material reveals a spectrum characteristic of graphene-based materials, with indications of defects and the presence of oxygen content. X-ray diffraction illustrates the characteristic graphitic lattice, with a slightly larger interlayer spacing attributed to intercalated functional groups. X-ray photoelectron spectroscopy confirms sp<sup>2</sup> hybridized carbon as the major component. High-resolution transmission electron microscopy provides insights into the multilayered structure and variations in interlayer spacing. The as-synthesized pristine graphene exhibits nearly ten times greater efficiency in adsorbing perfluorooctanoic acid compared to the oxidized form of graphene, although it is slightly less effective than graphene-based nanocomposites.","PeriodicalId":29791,"journal":{"name":"Small Science","volume":null,"pages":null},"PeriodicalIF":11.1000,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/smsc.202400176","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Microplastic pollution poses a growing threat to ecosystems globally, necessitating sustainable solutions. This study explores upcycling microplastics into graphene as a promising approach Traditional methods like pyrolysis and catalytic carbonization are slow and compromise graphene quality. Flash Joule heating is fast but energy-intensive and hard to control. In contrast, atmospheric pressure microwave plasma (APMP) synthesis, the proposed technique, offers a one-step, environmentally friendly alternative. APMP operates at relatively lower temperatures, reducing energy consumption and providing precise control over process parameters. This study demonstrates that polyethylene microplastics from waste dropper bottles can be efficiently transformed into graphene using APMP synthesis. Raman spectroscopy of synthesized material reveals a spectrum characteristic of graphene-based materials, with indications of defects and the presence of oxygen content. X-ray diffraction illustrates the characteristic graphitic lattice, with a slightly larger interlayer spacing attributed to intercalated functional groups. X-ray photoelectron spectroscopy confirms sp2 hybridized carbon as the major component. High-resolution transmission electron microscopy provides insights into the multilayered structure and variations in interlayer spacing. The as-synthesized pristine graphene exhibits nearly ten times greater efficiency in adsorbing perfluorooctanoic acid compared to the oxidized form of graphene, although it is slightly less effective than graphene-based nanocomposites.
期刊介绍:
Small Science is a premium multidisciplinary open access journal dedicated to publishing impactful research from all areas of nanoscience and nanotechnology. It features interdisciplinary original research and focused review articles on relevant topics. The journal covers design, characterization, mechanism, technology, and application of micro-/nanoscale structures and systems in various fields including physics, chemistry, materials science, engineering, environmental science, life science, biology, and medicine. It welcomes innovative interdisciplinary research and its readership includes professionals from academia and industry in fields such as chemistry, physics, materials science, biology, engineering, and environmental and analytical science. Small Science is indexed and abstracted in CAS, DOAJ, Clarivate Analytics, ProQuest Central, Publicly Available Content Database, Science Database, SCOPUS, and Web of Science.