Gelation of polymer solutions as a rheological phenomenon (mechanisms and kinetics)

IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Current Opinion in Colloid & Interface Science Pub Date : 2024-07-30 DOI:10.1016/j.cocis.2024.101844
Alexander Ya. Malkin , Svetlana R. Derkach
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Abstract

The phase equilibrium shift caused by changes in polymer-liquid compatibility under the influence of external or internal factors is discussed as the main mechanism of gel formation. Wherein, it is assumed that the gel is a solid, non-flowing soft substance formed due to incomplete phase decomposition of a solution. The sol-gel transition occurs through the intermediate stage of the formation of a viscoelastic yielding medium. The liquid-yielding medium-gel transition results in fundamental changes in the rheological properties of the substance. Therefore, the study of the kinetics of the evolution of rheological properties at various stages of gelation is an important tool for understanding this phenomenon. The review contains a discussion of recent publications and the formulation of some challenging problems.

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作为流变现象的聚合物溶液凝胶化(机理和动力学)
在外部或内部因素的影响下,聚合物与液体的相容性发生变化,从而导致相平衡移动,这是凝胶形成的主要机理。其中假定凝胶是由于溶液的不完全相分解而形成的固态非流动软物质。溶胶-凝胶转变发生在粘弹性屈服介质形成的中间阶段。液-屈服介质-凝胶转变导致物质的流变特性发生根本变化。因此,研究凝胶化各阶段流变特性演变的动力学是了解这一现象的重要工具。本综述讨论了近期发表的论文,并提出了一些具有挑战性的问题。
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来源期刊
CiteScore
16.50
自引率
1.10%
发文量
74
审稿时长
11.3 weeks
期刊介绍: Current Opinion in Colloid and Interface Science (COCIS) is an international journal that focuses on the molecular and nanoscopic aspects of colloidal systems and interfaces in various scientific and technological fields. These include materials science, biologically-relevant systems, energy and environmental technologies, and industrial applications. Unlike primary journals, COCIS primarily serves as a guide for researchers, helping them navigate through the vast landscape of recently published literature. It critically analyzes the state of the art, identifies bottlenecks and unsolved issues, and proposes future developments. Moreover, COCIS emphasizes certain areas and papers that are considered particularly interesting and significant by the Editors and Section Editors. Its goal is to provide valuable insights and updates to the research community in these specialized areas.
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