{"title":"Impacts of viscosity on bending behavior of the electrospun jet: Simulation model and experiment","authors":"","doi":"10.1016/j.polymer.2024.127529","DOIUrl":null,"url":null,"abstract":"<div><p>Numerous experimental data indicate that higher viscosity solutions make it easier to obtain coarser fibers. However, the influences of viscosity on the whipping behavior of the jet and their subsequent impacts on the formation of terminal fiber during electrospinning remain topics of ongoing research. Simulation model and experiment presented in this study aim to solve these problems. The simulation model alters the dimensionless parameter F<sub>ve</sub> to predict the impacts of different viscosities on the bending behavior of the electrospun jet, while the experiment observes this behavior under different viscosities by regulating the solution concentration. The consistency of the simulation and experimental data implies the accuracy of the conclusions in this paper. Furthermore, the simulation model and experiment have demonstrated that a higher viscosity jet results in a smaller radius of the jet trajectory and lower jet velocity, which in turn leads to the formation of coarser fiber.</p></div>","PeriodicalId":405,"journal":{"name":"Polymer","volume":null,"pages":null},"PeriodicalIF":4.1000,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0032386124008656","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Numerous experimental data indicate that higher viscosity solutions make it easier to obtain coarser fibers. However, the influences of viscosity on the whipping behavior of the jet and their subsequent impacts on the formation of terminal fiber during electrospinning remain topics of ongoing research. Simulation model and experiment presented in this study aim to solve these problems. The simulation model alters the dimensionless parameter Fve to predict the impacts of different viscosities on the bending behavior of the electrospun jet, while the experiment observes this behavior under different viscosities by regulating the solution concentration. The consistency of the simulation and experimental data implies the accuracy of the conclusions in this paper. Furthermore, the simulation model and experiment have demonstrated that a higher viscosity jet results in a smaller radius of the jet trajectory and lower jet velocity, which in turn leads to the formation of coarser fiber.
期刊介绍:
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.