Luminescent Ln-MOFs for Chemical Sensing Application on Biomolecules.

IF 8.2 1区 化学 Q1 CHEMISTRY, ANALYTICAL ACS Sensors Pub Date : 2024-09-27 Epub Date: 2024-08-28 DOI:10.1021/acssensors.4c00614
Ning Wu, Chunmiao Bo, Shengwei Guo
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Abstract

At present, the application of rare-earth organic frameworks (Ln-MOFs) in fluorescence sensing has entered rapid development and shown great potential in various analytical fields, such as environmental analysis, food analysis, drug analysis, and biological and clinical analysis by utilizing their internal porosity, tunable structural size, and energy transfer between rare-earth ions, ligands, and photosensitizer molecules. In addition, because the luminescence properties of rare-earth ions are highly dependent on the structural details of the coordination environment surrounding the rare-earth ions, and although their excitation lifetimes are long, they are usually not burst by oxygen and can provide an effective platform for chemical sensing. In order to further promote the development of fluorescence sensing technology based on Ln-MOFs, we summarize and review in detail the latest progress of the construction of Ln-MOF materials for fluorescence sensing applications and related sensor components, including design strategies, preparation methods, and modification considerations and initially propose the future development prospects and prospects.

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用于生物分子化学传感的发光 Ln-MOFs
目前,稀土有机框架(Ln-MOFs)在荧光传感方面的应用已进入快速发展阶段,并利用其内部多孔性、可调结构尺寸以及稀土离子、配体和光敏剂分子之间的能量转移,在环境分析、食品分析、药物分析、生物和临床分析等多个分析领域显示出巨大的潜力。此外,由于稀土离子的发光特性高度依赖于稀土离子周围配位环境的结构细节,虽然其激发寿命较长,但通常不会被氧气猝灭,可为化学传感提供有效的平台。为了进一步推动基于 Ln-MOFs 的荧光传感技术的发展,我们总结并详细综述了荧光传感应用 Ln-MOF 材料及相关传感元件构建的最新进展,包括设计策略、制备方法、改性注意事项等,并初步提出了未来的发展前景和展望。
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来源期刊
ACS Sensors
ACS Sensors Chemical Engineering-Bioengineering
CiteScore
14.50
自引率
3.40%
发文量
372
期刊介绍: ACS Sensors is a peer-reviewed research journal that focuses on the dissemination of new and original knowledge in the field of sensor science, particularly those that selectively sense chemical or biological species or processes. The journal covers a broad range of topics, including but not limited to biosensors, chemical sensors, gas sensors, intracellular sensors, single molecule sensors, cell chips, and microfluidic devices. It aims to publish articles that address conceptual advances in sensing technology applicable to various types of analytes or application papers that report on the use of existing sensing concepts in new ways or for new analytes.
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