Effect of Cr addition on the microstructure and mechanical properties of MoNbVTa0.5Crx refractory high-entropy alloys

Abstract

To increase strength and decrease density of traditional refractory high-entropy alloys (RHEAs), the MoNbVTa_0.5Cr_x RHEAs were synthesized by mechanical alloying (MA) and spark plasma sintering (SPS). The effect of Cr content on microstructure and mechanical properties of the MoNbVTa_0.5Cr_x RHEAs was systematically studied. The results showed the addition of Cr could refine the microstructure, decrease density and increase strength of RHEAs. The microstructure of the sintered alloy was composed of BCC phase and a small amount of oxide phase (Ta₂VO₆), and Ta₂OV₆ (200) has a semi-coherent relationship with BCC phase (110), with a lattice mismatch degree of 7.34 %. The compressive yield strength of the MoNbVTa_0.5Cr_x RHEAs initially increased and then decreased with increasing Cr content. The MoNbVTa_0.5Cr_0.75 RHEAs demonstrated the best mechanical properties, and the compressive yield strength and ultimate compressive strength at room temperature were 3180 MPa and 3596 MPa, respectively, which were far higher than traditional WNbMoTaV RHEAs. And the density of MoNbVTa_0.5Cr_0.75 RHEAs was 21 % lower than that of sintered WNbMoTaV RHEAs. The strengthening mechanism of sintered MoNbVTa_0.5Cr_x RHEAs involved O/C atoms interstitial solid solution strengthening, grain boundary strengthening, and metal atoms solid solution strengthening, while the contribution of oxide precipitation strengthening was negligible.