{"title":"Synthesis of Fe-Mo catalyst surfaces using plasma-assisted surface alloying for carbon nanotube growth by PECVD","authors":"","doi":"10.1016/j.vacuum.2024.113621","DOIUrl":null,"url":null,"abstract":"<div><p>Transition metal nanoparticles can act as seeds for the nucleation and growth of carbon nanotubes (CNTs). Adding molybdenum (Mo) to an iron (Fe) catalyst offers synergistic and beneficial features that enhance the yield of these nanostructures and influence their morphological and structural aspects. This study explored the development of Fe-Mo catalyst surfaces for CNT synthesis using a novel plasma-assisted surface alloying process. AISI 1005 low-carbon steel specimens were surface-alloyed with Mo by employing a DC argon-hydrogen mixed glow discharge at three different temperatures (800 °C, 1150 °C, and 1200 °C with an additional diffusion step). Subsequently, the Fe-Mo surfaces were used for CNT synthesis at 700 °C under a plasma-carburizing atmosphere (20 % CH<sub>4</sub> + 80 % H<sub>2</sub>). The morphological, chemical, and structural aspects were assessed using material characterization techniques. The results indicate that Mo-enrichment temperatures and the resulting Mo content on Fe-Mo surfaces directly influence catalytic CNT growth and nanostructure morphology. Mo-rich intermetallic phases up to 71 wt% Mo hinders the CNT nucleation, while Mo in solid solution (0.7 wt% Mo) enhances CNT yield and improves their structural aspects. This study proves the feasibility of plasma surface alloying to produce Fe-Mo catalytic surfaces by controlling the processing parameters.</p></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vacuum","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0042207X24006675","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Transition metal nanoparticles can act as seeds for the nucleation and growth of carbon nanotubes (CNTs). Adding molybdenum (Mo) to an iron (Fe) catalyst offers synergistic and beneficial features that enhance the yield of these nanostructures and influence their morphological and structural aspects. This study explored the development of Fe-Mo catalyst surfaces for CNT synthesis using a novel plasma-assisted surface alloying process. AISI 1005 low-carbon steel specimens were surface-alloyed with Mo by employing a DC argon-hydrogen mixed glow discharge at three different temperatures (800 °C, 1150 °C, and 1200 °C with an additional diffusion step). Subsequently, the Fe-Mo surfaces were used for CNT synthesis at 700 °C under a plasma-carburizing atmosphere (20 % CH4 + 80 % H2). The morphological, chemical, and structural aspects were assessed using material characterization techniques. The results indicate that Mo-enrichment temperatures and the resulting Mo content on Fe-Mo surfaces directly influence catalytic CNT growth and nanostructure morphology. Mo-rich intermetallic phases up to 71 wt% Mo hinders the CNT nucleation, while Mo in solid solution (0.7 wt% Mo) enhances CNT yield and improves their structural aspects. This study proves the feasibility of plasma surface alloying to produce Fe-Mo catalytic surfaces by controlling the processing parameters.
期刊介绍:
Vacuum is an international rapid publications journal with a focus on short communication. All papers are peer-reviewed, with the review process for short communication geared towards very fast turnaround times. The journal also published full research papers, thematic issues and selected papers from leading conferences.
A report in Vacuum should represent a major advance in an area that involves a controlled environment at pressures of one atmosphere or below.
The scope of the journal includes:
1. Vacuum; original developments in vacuum pumping and instrumentation, vacuum measurement, vacuum gas dynamics, gas-surface interactions, surface treatment for UHV applications and low outgassing, vacuum melting, sintering, and vacuum metrology. Technology and solutions for large-scale facilities (e.g., particle accelerators and fusion devices). New instrumentation ( e.g., detectors and electron microscopes).
2. Plasma science; advances in PVD, CVD, plasma-assisted CVD, ion sources, deposition processes and analysis.
3. Surface science; surface engineering, surface chemistry, surface analysis, crystal growth, ion-surface interactions and etching, nanometer-scale processing, surface modification.
4. Materials science; novel functional or structural materials. Metals, ceramics, and polymers. Experiments, simulations, and modelling for understanding structure-property relationships. Thin films and coatings. Nanostructures and ion implantation.