Silver doped Polypyrrole nanocomposite-based gas sensor for enhanced ammonia gas sensing performance at room temperature

IF 3.8 Q2 CHEMISTRY, PHYSICAL Chemical Physics Impact Pub Date : 2024-09-07 DOI:10.1016/j.chphi.2024.100722
Arunima Verma , Tanuj Kumar , Rahul Singhal
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Abstract

Nanocomposite, which comprise organic and inorganic materials have gained increasing interest in the application for enhanced sensing response to both reducing and oxidation gases. In this study, a nanocomposite is chemical polymerization synthesized by reinforcing Ag nanoparticles with different concentration doped into the matrix of Polypyrrole (PPy). This nanocomposite is used as a sensing platform for ammonia detection with different concentration (ppm). The homogeneous distribution of Ag nanoparticles onto the PPy matrix provides a smooth and dense surface area, further accelerating the transmission of electrons. The synergistic effect of PPy@Ag matrix is responsible for the outstanding conductivity, compatibility and catalytic power of the proposed gas sensor. The structure, morphology, and surface composition of as-synthesized samples were respectively, examined via X-ray diffraction, field emission scanning electron microscopy, Ultraviolet-visible spectroscopy, Thermogravimetric analysis and Fourier transform infrared spectroscopy. The results indicated that sensor based on the PPy@Ag5 (2 gm) nanocomposite showed the highest response toward ammonia as compare to pure PPy at room temperature with a response value is 58 % to 100 ppm. Overall, the obtained findings demonstrated that the PPy@Ag nanocomposite are promising materials for gas sensing applications in environmental monitoring.

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基于掺银聚吡咯纳米复合材料的气体传感器可在室温下提高氨气传感性能
由有机和无机材料组成的纳米复合材料在增强对还原性和氧化性气体的传感反应方面的应用越来越受到关注。在本研究中,通过在聚吡咯(PPy)基体中掺入不同浓度的银纳米粒子来增强纳米复合材料的化学聚合作用,合成了一种纳米复合材料。这种纳米复合材料被用作检测不同浓度(ppm)氨的传感平台。银纳米粒子均匀分布在聚吡咯基体上,形成了光滑致密的表面区域,进一步加速了电子的传输。PPy@Ag 矩阵的协同效应使该气体传感器具有出色的导电性、兼容性和催化能力。分别通过 X 射线衍射、场发射扫描电子显微镜、紫外可见光谱、热重分析和傅立叶变换红外光谱对合成样品的结构、形貌和表面成分进行了研究。结果表明,与纯 PPy 相比,基于 PPy@Ag5(2 克)纳米复合材料的传感器在室温下对氨气的响应最高,响应值为 58 % 至 100 ppm。总之,研究结果表明,PPy@Ag 纳米复合材料是环境监测中气体传感应用的理想材料。
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来源期刊
Chemical Physics Impact
Chemical Physics Impact Materials Science-Materials Science (miscellaneous)
CiteScore
2.60
自引率
0.00%
发文量
65
审稿时长
46 days
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