{"title":"Silver doped Polypyrrole nanocomposite-based gas sensor for enhanced ammonia gas sensing performance at room temperature","authors":"Arunima Verma , Tanuj Kumar , Rahul Singhal","doi":"10.1016/j.chphi.2024.100722","DOIUrl":null,"url":null,"abstract":"<div><p>Nanocomposite, which comprise organic and inorganic materials have gained increasing interest in the application for enhanced sensing response to both reducing and oxidation gases. In this study, a <span><span>nanocomposite</span><svg><path></path></svg></span> is chemical polymerization synthesized by reinforcing Ag <span><span>nanoparticles</span><svg><path></path></svg></span> with different concentration doped into the matrix of Polypyrrole (PPy). This <span><span>nanocomposite</span><svg><path></path></svg></span> is used as a sensing platform for ammonia detection with different concentration (ppm). The <span><span>homogeneous distribution</span><svg><path></path></svg></span> of Ag <span><span>nanoparticles</span><svg><path></path></svg></span> onto the PPy matrix provides a smooth and dense <span><span>surface area</span><svg><path></path></svg></span>, further accelerating the transmission of electrons. The <span><span>synergistic effect</span><svg><path></path></svg></span> of PPy@Ag matrix is responsible for the outstanding conductivity, compatibility and catalytic power of the proposed gas sensor. The structure, morphology, and surface composition of as-synthesized samples were respectively, examined via X-ray diffraction, field emission scanning electron microscopy, Ultraviolet-visible spectroscopy, Thermogravimetric analysis and Fourier transform infrared spectroscopy. The results indicated that sensor based on the PPy@Ag5 (2 gm) nanocomposite showed the highest response toward ammonia as compare to pure PPy at room temperature with a response value is 58 % to 100 ppm. Overall, the obtained findings demonstrated that the PPy@Ag nanocomposite are promising materials for gas sensing applications in environmental monitoring.</p></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667022424002664/pdfft?md5=0a4506bcdd540b6820fb0bb0e9a01188&pid=1-s2.0-S2667022424002664-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics Impact","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667022424002664","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Nanocomposite, which comprise organic and inorganic materials have gained increasing interest in the application for enhanced sensing response to both reducing and oxidation gases. In this study, a nanocomposite is chemical polymerization synthesized by reinforcing Ag nanoparticles with different concentration doped into the matrix of Polypyrrole (PPy). This nanocomposite is used as a sensing platform for ammonia detection with different concentration (ppm). The homogeneous distribution of Ag nanoparticles onto the PPy matrix provides a smooth and dense surface area, further accelerating the transmission of electrons. The synergistic effect of PPy@Ag matrix is responsible for the outstanding conductivity, compatibility and catalytic power of the proposed gas sensor. The structure, morphology, and surface composition of as-synthesized samples were respectively, examined via X-ray diffraction, field emission scanning electron microscopy, Ultraviolet-visible spectroscopy, Thermogravimetric analysis and Fourier transform infrared spectroscopy. The results indicated that sensor based on the PPy@Ag5 (2 gm) nanocomposite showed the highest response toward ammonia as compare to pure PPy at room temperature with a response value is 58 % to 100 ppm. Overall, the obtained findings demonstrated that the PPy@Ag nanocomposite are promising materials for gas sensing applications in environmental monitoring.